价格与库存信息目前不能提供
等级
purum
方案
≥99.0% (RT)
表单
solid
反应适用性
reagent type: catalyst
core: copper
mp
498 °C (lit.)
密度
4.77 g/mL at 25 °C (lit.)
SMILES字符串
Br[Cu]Br
InChI
1S/2BrH.Cu/h2*1H;/q;;+2/p-2
InChI key
QTMDXZNDVAMKGV-UHFFFAOYSA-L
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警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Lingling Chu et al.
Organic letters, 11(10), 2197-2200 (2009-04-22)
CuBr-catalyzed oxidative difluoromethylation of readily available tertiary amines with difluoroenol silyl ethers was performed under mild conditions to afford beta-amine-alpha,alpha-difluoro ketones.
Minhang Xin et al.
Steroids, 75(1), 53-56 (2009-10-20)
An efficient and practical scheme to synthesize 2-methoxyestradiol has been developed. The key step was the copper-mediated methoxylation using ethyl acetate as a co-catalyst to introduce a methoxyl group. These synthetic procedures of four steps from 17beta-estradiol as starting material
Jitender B Bariwal et al.
Organic letters, 12(12), 2774-2777 (2010-05-21)
An unprecedented, diversity-oriented strategy for the generation of 6,7-dihydro-5H-dibenzo[c,e]azepines and 5,6,7,8-tetrahydrodibenzo[c,e]azocines by a microwave-assisted copper-catalyzed intramolecular A(3)-coupling reaction is presented.
Robin B Bedford et al.
Dalton transactions (Cambridge, England : 2003), 39(43), 10464-10472 (2010-10-12)
The solvent-free, palladium-catalysed reaction of anilides with CuCl(2) in the presence or absence of copper acetate yields ortho-chlorinated anilides in good to excellent yields, even on a large scale (100 mmol). By contrast, the equivalent reactions with copper bromide, either
Shengqing Ye et al.
Chemical communications (Cambridge, England), (36)(36), 5406-5408 (2009-09-03)
Palladium-catalyzed tandem reactions of 2-alkenylphenyl-acetylenes with CuCl2 or CuBr2 afforded 3-chloro- or 3-bromo-1-methyleneindenes in good yields; these compounds could be further elaborated via palladium-catalyzed coupling reactions.
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