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Merck

437581

Sigma-Aldrich

氯仿

ACS reagent, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer

别名:

三氯甲烷

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About This Item

经验公式(希尔记法):
CHCl3
CAS号:
分子量:
119.38
Beilstein:
1731042
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:

等級

ACS reagent

品質等級

蒸汽密度

4.1 (vs air)

蒸汽壓力

160 mmHg ( 20 °C)

化驗

≥99.8%

形狀

liquid

包含

0.5-1.0% ethanol as stabilizer

包裝

PVC-coated bottle of 4x4 L

蒸發殘留物

≤0.001%

顏色

APHA: ≤10

折射率

n20/D 1.445 (lit.)

bp

60.5-61.5 °C (lit.)
60.5-61.5 °C

mp

−63 °C (lit.)

密度

1.492 g/mL at 25 °C (lit.)

正離子痕跡

Pb: ≤0.05 ppm

SMILES 字串

ClC(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H

InChI 密鑰

HEDRZPFGACZZDS-UHFFFAOYSA-N

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一般說明

Chloroform is a colorless, volatile chlorinated organic solvent whose vapors have narcotic effect. It is susceptible to degradation with time which can be suppressed by adding ethanol as a stabilizer. Since ethanol is added in higher concentration it leads to increase in polarity which may have a potential influence on some of the applications.

應用

Chloroform may be used in the following processes:
  • Synthesis of colloidal hydrophobic CdSe core nanocrystals (quantum dots).
  • Preparing phospholipid solutions.
  • As a solvent in the photolysis reaction of ruthenium complexes.
  • Solvent for recrystallization.
  • As a reference compound to detect the presence of chloroform in tobacco smokes.
  • As an extractant in solvent extraction process.

象形圖

Skull and crossbonesHealth hazard

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

標靶器官

Central nervous system, Liver,Kidney

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

does not flash

閃點(°C)

does not flash


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Systematic studies on the breakdown of p,p'-DDT in tobacco smokes. Presence of methyl chloride, dichloromethane, and chloroform in tobacco smokes.
Chopra NM and Sherman LR.
Analytical Chemistry, 44(6), 1036-1038 (1972)
Engineering of ultra-small diagnostic nanoprobes through oriented conjugation of single-domain antibodies and quantum dots.
Sukhanova A, et al.
Protocol Exchange (2012)
Eagleson M.
Concise Encyclopedia Chemistry, 216-216 (1994)
The affinity of two antimicrobial peptides derived from bovine milk proteins for model lipid membranes.
Barzyk W, et al.
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Kinetics and Mechanism of the Photooxidation of Bis (bipyridine) dichlororuthenium (II) and the Photoreduction of Bis (bipyridine) dichlororuthenium (III) in Chloroform.
Sathiyabalan S and Hoggard PE.
Inorganic Chemistry, 34(18), 4562-4571 (1995)

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