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Merck

156256

Sigma-Aldrich

甲醇钠 溶液

25 wt. % in methanol

别名:

甲氧基钠

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25 ML
$95.00
1 L
$139.00
2.5 L
$246.00

$95.00


国内现货,预计发货时间2025年4月11日详情


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25 ML
$95.00
1 L
$139.00
2.5 L
$246.00

About This Item

线性分子式:
CH3ONa
CAS号:
分子量:
54.02
Beilstein:
3592982
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.21

$95.00


国内现货,预计发货时间2025年4月11日详情


获取大包装报价

等级

for analytical purposes

质量水平

蒸汽密度

1.1 (vs air)

蒸汽压

50 mmHg ( 20 °C)
96 mmHg ( 25 °C)

表单

liquid

自燃温度

878 °F

浓度

25 wt. % in methanol

折射率

n20/D 1.37

密度

0.945 g/mL at 25 °C

SMILES字符串

[Na+].C[O-]

InChI

1S/CH3O.Na/c1-2;/h1H3;/q-1;+1

InChI key

WQDUMFSSJAZKTM-UHFFFAOYSA-N

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相关类别

一般描述

产品是25wt.%甲醇钠甲醇溶液。铜催化剂存在下,研究了不同反应条件下和非活性芳基溴化物反应。[1]在DMF(二甲基甲酰胺)钯催化剂存在情况下,它能和卤代芳烃反应生成芳烃。[2]

应用

甲醇钠可以用于合成含有NO的纳米颗粒(SNO-NP)。[3]
通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构,在基态时具有 24 个不成对电子。[4]

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 1

靶器官

Eyes,Central nervous system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

60.0 °F - closed cup - Solvent

闪点(°C)

15.55 °C - closed cup - Solvent


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Brian J Riley et al.
ACS applied materials & interfaces, 12(17), 19682-19692 (2020-04-16)
In this paper, sodium aluminosilicate aerogels and xerogels were evaluated as scaffolds for a variety of different getters including Ag+, Cs+, Cu2+, Fe3+, K+, Li+, Rb+, Sb3+, Sn2+, and Sn4+ for the capture of gaseous iodine coming from nuclear facilities.
Jessica Beekman et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 37(1), 48-60 (2019-10-10)
Fatty acid esters of 3-monochloropropanediol (3-MCPD), 2-monochlorpropanediol (2-MCPD), and glycidol are process-induced chemical contaminants found in refined vegetable oils. Due to their toxicological properties, there is potential concern regarding exposure to these compounds, particularly for formula-fed infants where refined edible
Palladium hydrides in organic synthesis. Reduction of aryl halides by sodium methoxide catalyzed by tetrakis (triphenylphosphine) palladium.
Zask A and Helquist P.
The Journal of Organic Chemistry, 43(8), 1619-1620 (1978)
Alex Schudel et al.
Nature nanotechnology, 15(6), 491-499 (2020-06-12)
Therapeutic delivery selectively to lymph nodes has the potential to address a variety of unmet clinical needs. However, owing to the unique structure of the lymphatics and the size-restrictive nature of the lymph node reticular network, delivering cargo to specific
Sonu Kumar et al.
Macromolecular bioscience, 20(6), e2000048-e2000048 (2020-04-15)
The synthesis and self-assembly of peptide-polymer conjugates into fibrillar nanostructures are reported, based on the amyloidogenic peptide KLVFF. A strategy for rational synthesis of polymer-peptide conjugates is documented via tethering of the amyloidogenic peptide segment LVFF (Aβ17-20 ) and its

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. HI, does the Sodium methoxide solution come in a Sure-seal bottle?

    1 answer
    1. Product 156256, Sodium methoxide solution is not packaged in a Sure/Seal™ bottle. The 156256-25mL, 156256-1L, and 156256-2.5L SKUs are packaged in amber glass bottles with PP caps and HDPE/PTFE liners. The 156256-18L is packaged in a carbon steel drum.

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