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Merck

155837

Sigma-Aldrich

四丁基硫酸氢铵

97%

别名:

Tetrabutylammonium bisulfate

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25 G
$129.00
100 G
$367.00
1 KG
$1,190.00

About This Item

线性分子式:
(CH3CH2CH2CH2)4N(HSO4)
CAS号:
分子量:
339.53
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.21

$129.00


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等級

for analytical purposes

品質等級

化驗

97%

形狀

solid

mp

169-171 °C (lit.)

應用

PFAS testing

官能基

amine

SMILES 字串

OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI 密鑰

SHFJWMWCIHQNCP-UHFFFAOYSA-M

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一般說明

四丁基硫酸氢铵是一种铵盐。它可以用作溶解钌(II)络合物 fac-[Ru(CO)2(H2O)3(C(O)C2H5)][CF3SO3]的溶剂。[1]它可作为制备交替聚酮和丙酸的反应介质中的助催化剂。[2]

應用

四丁基硫酸氢铵可用作糖基化1,4-二氢吡啶的绿色合成的催化剂。[3]
四丁基硫酸氢铵可用作糖基化1,4-二氢吡啶的绿色合成的催化剂。[3]
四丁基硫酸氢铵可作为离子对试剂,通过气相色谱(GC)方法测定:
  • 直链烷基苯磺酸盐(LASs)[4]
  • 酸性除草剂[5]

法律資訊

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

348.1 °F - closed cup

閃點(°C)

175.6 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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New media in homogeneous catalysis: wet sodium or tetrabutylammonium hydrogensulfate salts for reppe syntheses catalyzed by a ru (ii) carbonyl complex.
Pardey AJ, et al.
Journal of Coordination Chemistry, 57(10), 871-882 (2004)
Derivatization and solid-phase microextraction
Stashenko.EE and Martinez.RJ
TrAC, Trends in Analytical Chemistry, 23(8), 553-561 (2004)
Tetrabutylammonium hydrogen sulfate catalyzed eco-friendly and efficient synthesis of glycosyl 1, 4-dihydropyridines.
Tewari N, et al.
Tetrahedron Letters, 45(49), 9011-9014 (2004)
Hydrocarboxylation and stepwise alternating oligomerization of carbon monoxide and ethylene catalyzed by cis-[Rh(CO)2(amine)2](PF6) complexes in a wet liquid tetrabutylammonium hydrogensulfate.
Pardey AJ, et al.
Polyhedron, 23(10), 1677-1683 (2004)
Environmental and bioanalytical applications of hollow fiber membrane liquid-phase microextraction: a review
Lee J, et al.
Analytica Chimica Acta, 624(2), 253-268 (2008)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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