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11291

Sigma-Aldrich

1-乙基-3-甲基咪唑啉双(三氟甲基磺酰基)亚胺

≥97.0% (NMR)

别名:

EMIM BTI, EMIM TFSI, EMIMIm

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1 G
$328.00
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$686.00

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$328.00
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About This Item

经验公式（希尔记法）:
C8H11F6N3O4S2
CAS号:
174899-82-2
分子量:
391.31
MDL编号:
MFCD03788927
UNSPSC代码:
12352100
PubChem化学物质编号:
329749349
NACRES:
NA.22

$328.00

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质量水平

100

方案

≥97.0% (NMR)

表单

liquid

杂质

<0.5% water

mp

≥−15 °C (lit.)

官能团

fluoro

SMILES字符串

CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1

InChI key

LRESCJAINPKJTO-UHFFFAOYSA-N

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一般描述

1-乙基-3-甲基咪唑双（三氟甲基磺酰基）酰亚胺[EMIM] [N（Tf）2]是一种室温离子液体（RTIL）。[1]（[EMIM] [N（TF）2]）作为非水溶剂，由于其具有低蒸气压、高热稳定性、良好的导电性和宽的电化学窗口，因此在电活性物质的电化学研究中优于传统的非质子极性有机溶剂。[2][3][EMIM] [N（TF）2]在CO2中显示出良好的溶解性。[4]

应用

[EMIM] [N（TF）2]在微波条件下，可以用作合成氧化锌（ZnO）纳米颗粒的绿色溶剂。[5]它适用于需要具有高CO2溶解度的溶剂的反应。[4]

外形

疏水性氟化离子液体

其他说明

在离子液体中进行对映选择性反应[6][7]

法律信息

产品受美国专利 5,827,602 保护，转让给 Covalent Associates, Inc. Woburn, Ma, USA

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H301

危险分类

Acute Tox. 3 Oral

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
WXBF2678V
BCCG6193
BCCD6901
BCCC0151
BCBX9586

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Green synthesis of ZnO nanoparticles in a room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Goharshadi EK, et al.
Journal of Physics and Chemistry of Solids, 69(8), 2057-2060 (2008)
Kinetic analysis of the reaction between electrogenerated superoxide and carbon dioxide in the room temperature ionic liquids 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide and hexyltriethylammonium bis (trifluoromethylsulfonyl) imide
Buzzeo, Marisa C., et al.
The Journal of Physical Chemistry B, 108.12, 3947-3954 (2004)
Investigation on physical and electrochemical properties of three imidazolium based ionic liquids (1-hexyl-3-methylimidazolium tetrafluoroborate, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide and 1-butyl-3-methylimidazolium methylsulfate)
Beigi, Ali Akbar Miran, et al.
Journal of Molecular Liquids, 177, 361-368 (2013)
Raman and ab initio study of the conformational isomerism in the 1?ethyl?3?methyl?imidazolium bis (trifluoromethanesulfonyl) imide ionic liquid
Lassegues, J. C., et al.
Journal of Raman Spectroscopy, 38.5, 551-558 (2007)
Liquid? liquid equilibria in binary mixtures containing substituted benzenes with ionic liquid 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide
Shiflett, Mark B., and Anne Marie S. Niehaus
Journal of Chemical and Engineering Data, 55.1, 346-353 (2009)
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Ionic Liquids: Electrochemical Apps

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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