If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
等级
for synthesis
synthesis grade
质量水平
蒸汽压
72 hPa ( 20 °C)
方案
≥99% (GC)
表单
liquid
自燃温度
215 °C
效能
730 mg/kg LD50, oral (Rat)
expl. lim.
1.2-9.3 % (v/v)
dilution
(for synthesis)
pH值(酸碱度)
12.7 (15 °C, 100 g/L in H2O, IUCLID)
沸点
90 °C/1013 hPa
mp
-115 °C
转变温度
flash point -11 °C
溶解性
133 g/L
密度
0.73 g/cm3 at 20 °C
储存温度
2-30°C
SMILES字符串
N(CC)(CC)CC
InChI
1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI key
ZMANZCXQSJIPKH-UHFFFAOYSA-N
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一般描述
应用
- 作为催化剂参与1,3-噻唑烷二酮、丙二腈和芳香醛的Domino 开环/再环化反应合成多取代二氢噻吩。
- 伯胺和磺酰化剂合成磺胺的反应中的碱。
- 钯催化 Suzuki-Heck 级联反应的溶剂
分析说明
密度(d 20 °C/20 °C):0.726 - 0.728
水(K. F.): ≤ 0.20 %
同一性(IR):通过测试
警示用语:
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
12.2 °F - closed cup
闪点(°C)
-11 °C - closed cup
实验方案
HPTLC–MS analysis of quinine in tonic water and caffeine in coffee and cola drinks.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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