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Merck
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文件

P55708

Sigma-Aldrich

(R)-(+)-胡薄荷酮

85%, technical grade

别名:

(+)-蒲勒酮, (R)-(+)-长叶薄荷酮, (R)-2-异亚丙基-5-甲基环己酮, 长叶薄荷酮

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About This Item

经验公式（希尔记法）:
C10H16O
CAS号:
89-82-7
分子量:
152.23
Beilstein:
2040703
EC號碼:
201-943-2
MDL號碼:
MFCD00063000
分類程式碼代碼:
85151701
PubChem物質ID:
24898670
NACRES:
NA.22

等級

technical grade

品質等級

100

蒸汽壓力

138 mmHg ( 25 °C)

化驗

85%

光學活性

[α]20/D +22°, neat

折射率

n20/D 1.486 (lit.)

bp

224 °C (lit.)

密度

0.937 g/mL at 25 °C (lit.)

SMILES 字串

C[C@@H]1CC\C(=C(\C)C)C(=O)C1

InChI

1S/C10H16O/c1-7(2)9-5-4-8(3)6-10(9)11/h8H,4-6H2,1-3H3/t8-/m1/s1

InChI 密鑰

NZGWDASTMWDZIW-MRVPVSSYSA-N

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相关类别

一般說明

(R)-(+)-Pulegone, a monoterpene ketone found in essential oil of pennyroyal, can induce abortion.

應用

(R)-(+)-Pulegone may be used as a starting material to synthesize:
  • (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane, a spiroketal
  • (R)-(+)-citronellic acid, an intermediate to prepare leucine-d3
  • (+)-fawcettidine, a Lycopodium alkaloid

象形圖

Health hazardExclamation mark
GHS08,GHS07

訊號詞

Warning

危險聲明

H302,H351

危險分類

Acute Tox. 4 Oral - Carc. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 1

閃點（°F）

179.6 °F - closed cup

閃點（°C）

82 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Synthesis of (2S, 4S)-and (2S, 4R)-[5,5,5-2H3] leucine from (R)-pulegone.
Hill RK, et al.
Canadian Journal of Chemistry, 72(1), 110-113 (1994)
Total Synthesis of (+)-Fawcettidine.
Kozak JA and Dake GR.
Angewandte Chemie (International Edition in English), 47(22), 4221-4223 (2008)
Metabolism of (R)-(+)-pulegone in F344 rats.
Chen LJ, et al.
Drug Metabolism and Disposition, 29(12), 1567-1577 (2001)
From (R)-(+)-pulegone to (2S,4R,6R,8S)-2,4,8-trimethyl-1,7-dioxaspiro[5.5]undecane-A unique spiroacetal from the insect Kingdom.
Tu YQ, et al.
Tetrahedron Asymmetry, 6(2), 397-400 (1995)
Mitscheli S Da Rocha et al.
Toxicological sciences : an official journal of the Society of Toxicology, 128(1), 1-8 (2012-04-14)
Essential oils from mint plants, including peppermint and pennyroyal oils, are used at low levels as flavoring agents in various foods and beverages. Pulegone is a component of these oils. In a 2-year bioassay, oral administration of pulegone slightly increased
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