跳转至内容
Merck

M46055

Sigma-Aldrich

3-亚甲基-2-降冰片酮

97%

别名:

3-methylene-bicyclo[2,2,1]heptan-2-one

登录查看公司和协议定价


About This Item

经验公式(希尔记法):
C8H10O
CAS号:
分子量:
122.16
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
如需咨询该产品M46055,请联系默克当地办事处或经销商。 联系技术服务部门

方案

97%

折射率

n20/D 1.493 (lit.)

沸点

69-71 °C/11 mmHg (lit.)

密度

0.997 g/mL at 25 °C (lit.)

SMILES字符串

C=C1[C@@H]2CC[C@@H](C2)C1=O

InChI

1S/C8H10O/c1-5-6-2-3-7(4-6)8(5)9/h6-7H,1-4H2/t6-,7+/m1/s1

InChI key

FNOOZJAPZFHNCW-RQJHMYQMSA-N

应用

3-Methylene-2-norbornanone can be used as a reactant to prepare:
  • 3-(2-(4-methoxyphenyl)-2-oxoethyl)bicyclo[2.2.1]heptan-2-one by reacting with 4-anisaldehyde in the presence of tetrabutylammonium decatungstate (TBADT) photocatalyst.[1]
  • 2-Aryl-3-methylene-endo-norbornanols by treating with corresponding aryl lithium reagents.[2]

象形图

Flame

警示用语:

Warning

危险声明

危险分类

Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

131.0 °F - closed cup

闪点(°C)

55 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本?

如果您需要特殊版本,可通过批号或批次号查找具体证书。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Structural effects in solvolytic reactions. 32. Effect of increasing electron demand on the rates of solvolysis of 2-aryl-3-methylene-2-norbornyl p-nitrobenzoates. High exo/endo rate and product ratios for tertiary derivatives of the accepted classical 3-methylene-2-norbornyl system
Brown HC and Rao C G
The Journal of Organic Chemistry, 44(20), 3536-3540 (1979)
Masayuki Takaishi et al.
The journal of physiological sciences : JPS, 64(1), 47-57 (2013-10-15)
TRPA1, one of the transient receptor potential channels, has been reported to be involved in nociception and inflammatory pain, suggesting that this molecule could be a promising target for the development of analgesic agents. We screened several monoterpene analogs of
Benzoyl radicals from (hetero) aromatic aldehydes. Decatungstate photocatalyzed synthesis of substituted aromatic ketones
Ravelli D, et al.
Organic & Biomolecular Chemistry, 8(18), 4158-4164 (2010)

Questions

Reviews

No rating value

Active Filters

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门