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Merck

M29908

Sigma-Aldrich

苯甲酸甲酯

99%

别名:

苯甲酸甲酯

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25 G
$58.00
500 G
$83.80
3 KG
$330.00

$58.00


预计发货时间2025年4月21日详情


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25 G
$58.00
500 G
$83.80
3 KG
$330.00

About This Item

线性分子式:
C6H5COOCH3
CAS号:
分子量:
136.15
Beilstein:
1072099
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$58.00


预计发货时间2025年4月21日详情


获取大包装报价

蒸汽密度

4.68 (vs air)

蒸汽压

<1 mmHg ( 20 °C)

方案

99%

表单

liquid

折射率

n20/D 1.516 (lit.)

沸点

198-199 °C (lit.)

mp

−12 °C (lit.)

溶解性

H2O: soluble 2.1 g/L at 20 °C

密度

1.088 g/mL at 20 °C (lit.)

SMILES字符串

COC(=O)c1ccccc1

InChI

1S/C8H8O2/c1-10-8(9)7-5-3-2-4-6-7/h2-6H,1H3

InChI key

QPJVMBTYPHYUOC-UHFFFAOYSA-N

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一般描述

苯甲酸甲酯是一种挥发性芳香族酯化合物,广泛用于香料工业。[1][2]这种成分在番石榴、芒果和奇异果中天然存在。

应用

苯甲酸甲酯(C6H5CO2CH3)可用作以下反应的前体:
  • 使用载体锰氧化物催化剂选择性合成苯甲醛。[3][4];
  • 通过傅-克酰基化与芳基化合物反应制备二苯甲酮衍生物。[5]

象形图

Health hazardExclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral - Repr. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 1

闪点(°F)

170.6 °F - Pensky-Martens closed cup

闪点(°C)

77 °C - Pensky-Martens closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Characterization and Activity of MnO/γ-Al2O3 for Hydrogenation of Methyl Benzoate to Benzaldehyde
Xu H-L, et al.
Chin. J. Chem., 19(7), 647-651 (2001)
Direct aerobic oxidation of primary alcohols to methyl esters catalyzed by a heterogeneous gold catalyst
Nielsen IS, et al.
Catalysis Letters, 116(1-2), 35-40 (2007)
Hydrogenation of methyl benzoate to benzaldehyde over manganese oxide catalysts prepared from Mg/Mn/Al hydrotalcite-like compounds
Chen A, et al.
Applied Catalysis A: General, 274(1-2), 101-109 (2004)
N Dudareva et al.
The Plant cell, 12(6), 949-961 (2000-06-15)
In snapdragon flowers, the volatile ester methyl benzoate is the most abundant scent compound. It is synthesized by and emitted from only the upper and lower lobes of petals, where pollinators (bumblebees) come in contact with the flower. Emission of
Nan Zhao et al.
Plant physiology and biochemistry : PPB, 48(4), 279-287 (2010-03-05)
Two benzenoid esters, methyl salicylate (MeSA) and methyl benzoate (MeBA), were detected from insect-damaged rice plants. By correlating metabolite production with gene expression analysis, five candidate genes encoding putative carboxyl methyltransferases were identified. Enzymatic assays with Escherichia coli-expressed recombinant proteins

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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