推荐产品
方案
≥99.85%
表单
foil
制造商/商品名称
Goodfellow 877-426-59
电阻率
4.33 μΩ-cm, 20°C
沸点
3727 °C (lit.)
mp
1966 °C (lit.)
密度
12.41 g/cm3 (lit.)
SMILES字符串
[Rh]
InChI
1S/Rh
InChI key
MHOVAHRLVXNVSD-UHFFFAOYSA-N
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一般描述
For updated SDS information please visit www.goodfellow.com.
法律信息
Product of Goodfellow
储存分类代码
13 - Non Combustible Solids
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Huw M L Davies et al.
Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)
This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.
Denise A Colby et al.
Chemical reviews, 110(2), 624-655 (2009-05-15)
Albert Padwa
Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)
In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and
Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
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