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Merck
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文件

D194255

Sigma-Aldrich

1,3-二硝基苯

97% anhydrous basis

别名:

1,3-二硝基苯, DNB, 间二硝基苯

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About This Item

线性分子式:
C6H4(NO2)2
CAS号:
99-65-0
分子量:
168.11
Beilstein:
1105654
EC號碼:
202-776-8
MDL號碼:
MFCD00007222
分類程式碼代碼:
12352100
PubChem物質ID:
24893577
NACRES:
NA.22

化驗

97% anhydrous basis

形狀

solid

雜質

≤10.0% H2O

bp

297 °C (lit.)

mp

84-86 °C (lit.)

密度

1.368 g/mL at 25 °C (lit.)

SMILES 字串

[O-][N+](=O)c1cccc(c1)[N+]([O-])=O

InChI

1S/C6H4N2O4/c9-7(10)5-2-1-3-6(4-5)8(11)12/h1-4H

InChI 密鑰

WDCYWAQPCXBPJA-UHFFFAOYSA-N

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相关类别

一般說明

1,3-二硝基苯可通过碱性抗坏血酸维的还原降解生成1,3-苯二胺。

應用

1,3-二硝基苯可用作反应物来合成：      
  • 2′,6′-二硝基联苯-4-醇和 1-硝基二苯并呋喃分别与 4-碘苯酚和 2-碘苯酚通过铜催化的区域选择性交叉偶联反应。      
  • 1H-吲唑衍生物，通过在碱催化剂存在下与各种 N-甲苯磺酰腙反应。      
  • 3-（1H-四唑-1-基）苯胺，在三官能氧化还原催化体系存在下与原甲酸三乙酯和 NaN3 反应。

訊號詞

Danger

危險分類

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

302.0 °F - closed cup

閃點（°C）

150 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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