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Merck

925772

Sigma-Aldrich

N,N′-Tetra(4-biphenyl)benzidine

≥97%

别名:

TBBDAz

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About This Item

经验公式(希尔记法):
C60H44N2
分子量:
793.00
MDL號碼:
分類程式碼代碼:
12352116
NACRES:
NA.21

描述

PL: 425 nm (in DCM)

品質等級

化驗

≥97%

形狀

powder

顏色

white to light yellow

軌道能量

HOMO 5.3 eV 
LUMO 2.2 eV 

紫外吸收

λ: 357 nm Amax: in DCM

InChI

1S/C60H44N2/c1-5-13-45(14-6-1)49-21-33-55(34-22-49)61(56-35-23-50(24-36-56)46-15-7-2-8-16-46)59-41-29-53(30-42-59)54-31-43-60(44-32-54)62(57-37-25-51(26-38-57)47-17-9-3-10-18-47)58-39-27-52(28-40-58)48-19-11-4-12-20-48/h1-44H

InChI 密鑰

WXAIEIRYBSKHDP-UHFFFAOYSA-N

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應用

Having N,N′-bis-(3-methylphenyl)-N,N′-bis-phenyl-benzidine (TPD) like unit, TBBDA (BPBPA) is electron-rich. As a result, it is used as a hole-transport material in organic light-emitting diodes (OLED).
Example of OLED Device Performance:
ITO/DNTPD (60 nm)/BPBPA (30 nm)/mCBP (10 nm)/mCBP:Ir(dbi)3 (30 nm)/LG201 (35 nm)/
LiF (1 nm)/Al (200 nm)
Color: blue
EQE: Not known
Turn-On Voltage: 2.8V
Max. Luminance: ~ 9900 Cd/m2

Besides, for organic solar cell (OSCs) applications, its highest occupied molecular orbital energy value at 5.3 eV is well matched with a donor layer and its high mobility of 1.74 × 10-2 cm2/Vs brings out an easy and rapid extraction of holes from the donor material.
N,N′-Tetra(4-biphenyl)benzidine can be used as an emissive layer or hole transporting material in studies such as organic light-emitting diodes (OLEDs), photovoltaics, organic field-effect transistors (OFETs).

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3


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Four times lifetime improvement of blue phosphorescent organic light-emitting diodes by managing recombination zone.
Jeon S K, et al.
Organic Electronics, 27, 202-206 (2015)
Superb lifetime of blue organic light-emitting diodes through engineering interface carrier blocking layers and adjusting electron leakage and an unusual efficiency variation at low electric field.
Kim T,et al.
Journal of Material Chemistry C, 6, 8472-8478 (2018)

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