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Merck

909734

Sigma-Aldrich

1-Phenyl-2-((trifluoromethyl)sulfonyl)propan-1-one

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About This Item

经验公式(希尔记法):
C10H9F3O3S
分子量:
266.24
UNSPSC代码:
12352101

表单

crystals

反应适用性

reaction type: C-C Bond Formation

官能团

fluoro
ketone
phenyl
sulfone

储存温度

−20°C

应用

1-Phenyl-2-((trifluoromethyl)sulfonyl)propan-1-one is part of a suite of reagents developed by the Li group for late-stage functionalization of pharmaceutically relevant compounds. The reagents serve as precursors to alkyl radicals generated under light mediated, redox-neutral and catalyst free conditions for use in the Minisci alkylation of aromatics.

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

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Peng Liu et al.
Journal of the American Chemical Society, 139(40), 14315-14321 (2017-10-03)
The Minisci alkylation is useful to functionalize aromatics via alkyl radical addition. Current approaches to prepare alkyl radicals follow either oxidative or reductive pathways from various functional groups. Developing new strategy beyond these traditional methods remains elusive yet highly significant.

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