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化驗
≥95%
形狀
powder
反應適用性
reagent type: catalyst
reaction type: C-C Bond Formation
mp
112-116 °C
儲存溫度
2-8°C
應用
Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides.
其他說明
Site-Specific Deoxyfluorination of Small Peptides with [18F]Fluoride
Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions
Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+
Comparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions
Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Jens Rickmeier et al.
Angewandte Chemie (International ed. in English), 57(43), 14207-14211 (2018-09-07)
Radiolabeled receptor-binding peptides are an important class of positron emission tomography tracers owing to achievable high binding affinities and their rapid blood clearance. Herein, a method to introduce a 4-[18 F]fluoro-phenylalanine residue into peptide sequences is reported, by chemoselective radio-deoxyfluorination
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