901742

Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride

≥95%

• 别名: (^PyrN^MeNN)Ni-Cl, (SP-4-4)-Chloro[N₁,N₁-dimethyl-N₂-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN₁,κN₂]nickel, Second-generation Nickamine
• 经验公式（希尔记法）: C₁₈H₂₂ClN₃Ni
• 分子量: 374.53
• 分類程式碼代碼: 12352101

属性

• 化驗: ≥95%
• 形狀: powder or crystals
• 反應適用性: core: nickel; reagent type: catalyst
• SMILES 字串: CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl

说明

應用

As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.

其他說明

From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

安全信息

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable