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Merck

317624

Sigma-Aldrich

异佛尔酮二异氰酸酯

98%, mixture of isomers

别名:

1,3,3-三甲基-5-异氰酸基-1-异氰酸甲基环己烷

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5 ML
$79.20
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5 ML
$79.20
250 ML
$214.00
1 L
$432.00

About This Item

线性分子式:
OCNC6H7(CH3)3CH2NCO
分子量:
222.28
Beilstein:
2726467
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

$79.20


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质量水平

方案

98%

表单

liquid

折射率

n20/D 1.484 (lit.)

沸点

158-159 °C/15 mmHg (lit.)

密度

1.049 g/mL at 25 °C (lit.)

SMILES字符串

CC1(C)CC(CC(C)(CN=C=O)C1)N=C=O

InChI

1S/C12H18N2O2/c1-11(2)4-10(14-9-16)5-12(3,6-11)7-13-8-15/h10H,4-7H2,1-3H3

InChI key

NIMLQBUJDJZYEJ-UHFFFAOYSA-N

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一般描述

异佛尔酮二异氰酸酯(IPDI)是脂肪族二异氰酸酯,主要通过形成 −NCO连接用作固化剂。 它主要用于制备各种高性能涂料中的各种聚氨酯产品,可用于汽车和工业应用、医疗设备、室内装饰、绝缘和包装应用,并可用于制造粘结剂、密封剂和胶粘剂。由于存在脂族环,可制成抗紫外线膜。[1][2][3][4]

应用

IPDI主要用作生产聚氨酯树脂和弹性体的二异氰酸盐酯单体。IPDI 容易反应,可用于生产性质不同的聚合物产品,包括刚性和弹性产品。IPDI在聚合物工业中的主要用途包括:
  • 用于汽车和工业应用的聚氨酯涂料的生产。
  • 用于医疗设备和运动器材的聚氨酯弹性体的合成。
  • 用于室内装饰、绝缘和包装应用的聚氨酯泡沫的生产。
  • 用于粘结剂、密封剂和胶粘剂的制造。
  • 用于通过与3-氨基丙基三乙氧基硅烷的溶胶凝胶缩聚反应,合成桥联倍半硅氧烷(BSQ)。BSQ聚合物可用于制备紫外滤光片的防潮膜。
  • 作为修补剂用于通过界面聚合反应制备聚氨酯微胶囊。
  • 作为单体用于通过沉淀聚合反应合成高度单分散的聚脲微球。

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Aquatic Chronic 2 - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

闪点(°F)

325.4 °F - closed cup

闪点(°C)

163 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis of isophorone diisocyanate (IPDI) based waterborne polyurethanes: Comparison between zirconium and tin catalysts in the polymerization process
Sardon H, et al.
Progress in Organic Coatings, 66(3), 291-295 (2009)
Fernando Javier Aguilar-Pérez et al.
Journal of biomaterials science. Polymer edition, 30(15), 1415-1432 (2019-06-25)
Polyurethanes (PU) foams with titanium particles (Ti) were prepared with castor oil (CO) and isophorone diisocyanate (IPDI) as polymeric matrix, and 1, 3 and 5 wt.% of Ti. Composites were physicochemically and mechanically characterized and their biocompatibility assessed using human dental
Alger MSM
Polymer Science Dctionary null
Polyurethanes based on castor oil: kinetics, chemical, mechanical and thermal properties
Hablot E, et al.
Macromolecular Materials and Engineering, 293(11), 922-929 (2008)
Facile synthesis of bio-sourced polyurethane-fluorosilane modified TiO 2 hybrid coatings for high-performance self cleaning application
Yesudass SA, et al.
Journal of Polymer Research, 25(2), 34-34 (2018)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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