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Merck

88733

Sigma-Aldrich

(R)-1-[(SP)-2-(二环己基膦)二茂铁基]乙基二叔丁基膦

≥97%

别名:

(2R)-1-[(1R)-1-[双(1,1-二甲基乙基)膦]乙基]-2-(二环己基膦)二茂铁(符合 CAS 规范), Josiphos SL-J009-1

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About This Item

经验公式(希尔记法):
C32H52FeP2
分子量:
554.55
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
NACRES:
NA.22
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方案

≥97%

表单

powder

光学纯度

ee: ≥99%

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

官能团

phosphine

SMILES字符串

[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C

InChI

1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m1../s1

InChI key

FFFWTQLOUUWUJJ-GHVWMZMZSA-N

一般描述

(R)-1-[(SP)-2-(二环己基膦基)二茂铁基]乙基二-丁基膦(CyPF-tBu)是一种手性二茂铁基二膦配体。[1]
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应用

在钯催化的芳基溴化物/芳基三氟甲磺酸酯与硫代乙酸钾的异交叉偶联中,它可以用作配体,形成 S-芳基硫代乙酸酯。[2]

包装

无底玻璃瓶。内容物在插入式融锥内。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A simple, base-free preparation of S-aryl thioacetates as surrogates for aryl thiols.
van den Hoogenband A, et al.
Tetrahedron Letters, 51(52), 6877-6881 (2010)
Privileged ligands
Aldrich Chemfiles, 6(8), 12-12 null

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