804177

SnAP 3-Spiro-(2-Pyr) M试剂

• 经验公式（希尔记法）: C₂₃H₄₈N₂O₃Sn
• 分子量: 519.35
• UNSPSC代码: 12352103
• PubChem化学物质编号: 329768849
• NACRES: NA.22

属性

• 表单: liquid
• 质量水平: 100
• 折射率: n/D 1.489
• 密度: 1.122
• 官能团: ether
• 储存温度: −20°C
• SMILES字符串: CCCC[Sn](CCCC)(COCC1(CN(C(OC(C)(C)C)=O)CC1)N)CCCC
• InChI: 1S/C11H21N2O3.3C4H9.Sn/c1-10(2,3)16-9(14)13-6-5-11(12,7-13)8-15-4;3*1-3-4-2;/h4-8,12H2,1-3H3;3*1,3-4H2,2H3;
• InChI key: JLZWEXDNLRNRBE-UHFFFAOYSA-N

说明

一般描述

The product is a substituted SnAP [Sn(tin) amino protocol] reagent. SnAP reagents are air and moisture stable.

应用

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

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其他说明

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles

安全信息

• 象形图: GHS06,GHS08,GHS09
• 警示用语：: Danger
• 危险声明: H301,H312,H315,H319,H360FD,H372,H410
• 预防措施声明: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• 危险分类: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
• 储存分类代码: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3