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Merck

771953

Sigma-Aldrich

exo-5-Norbornene-2-methanol

≥99% (exo)

别名:

exo-5-Norbornenyl methyl alcohol

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About This Item

经验公式(希尔记法):
C8H12O
CAS号:
分子量:
124.18
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23

质量水平

方案

≥99% (exo)

表单

liquid

折射率

n20/D 1.499

沸点

200-205/760 mmHg

密度

1.030 at 25 °C

SMILES字符串

OCC1C[C@@H]2C[C@H]1C=C2

InChI

1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1

InChI key

LUMNWCHHXDUKFI-KJFJCRTCSA-N

一般描述

Exo-5-Norbornene-2-methanol is a norbornene derivative which is widely used as a monomer in the synthesis of polynorbornenes by vinyl polymerisation or ring opening methathesis polymerisation (ROMP). They are also used as a monomer or an intermediate in the synthesis of photoresist materials. This material is also widely used as an intermediate in the synthesis of pharmaceutically and biologically active compounds.[1]

应用

Used as a monomer in the synthesis of polynorbornenes by ring opening metathesis polymerisation.[2]

特点和优势

  • Produces polymers with high thermal stability and transparency which are useful for optical applications.[1]

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Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

195.0 °F

闪点(°C)

90.55 °C


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Stereo-Selective Synthesis of 5-Norbornene-2-exo-carboxylic Acid-Rapid Isomerization and Kinetically Selective Hydrolysis.
Kanao, M., Otake, A., Tsuchiya, K., & Ogino, K.
International Journal of Organic Chemistry, 2, 26-30 (2012)
Water-soluble polymers from acid-functionalized norbornenes
Lienkamp, K., Kins, C. F., Alfred, S. F., Madkour, A. E., & Tew, G. N.
Journal of Polymer Science Part A: Polymer Chemistry, 47(5), 1266-1273 (2009)

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