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Merck

740810

Sigma-Aldrich

2-(十二烷基硫基硫代羰基硫基)-2-甲基丙酸五氟苯基酯

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About This Item

经验公式(希尔记法):
C23H31F5O2S3
分子量:
530.68
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.23

形狀

liquid

雜質

4-5% pentafluorophenol

折射率

n20/D 1.512

密度

1.203 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCCSC(=S)SC(C)(C)C(=O)Oc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C23H31F5O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-32-22(31)33-23(2,3)21(29)30-20-18(27)16(25)15(24)17(26)19(20)28/h4-14H2,1-3H3

InChI 密鑰

XBUCQRRMAZYXHN-UHFFFAOYSA-N

一般說明

需要帮助选择正确的RAFT试剂?请查阅RAFT试剂与单体的相容性表。

應用

用于受控自由基聚合的RAFT试剂,特别适用于苯乙烯、丙烯酸酯、丙烯酰胺单体的聚合。链转移剂(CTA)

其他說明

该产品含有4-5%的五氟苯酚杂质。 该杂质通常不会干扰链转移剂

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

>230.0 °F

閃點(°C)

> 110 °C


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

实验方案

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

相关内容

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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