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731277

Sigma-Aldrich

2-氰基-2-丙基-4-氰基苯二硫代碳酸酯

98% (HPLC)

别名:

2-氰基丙基-4-氰基二硫代苯甲酸酯, 4-氰基苯硫代碳酸-1-氰基-1-甲基乙酯

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1 G
$195.00

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1 G
$195.00

About This Item

经验公式（希尔记法）:
C12H10N2S2
CAS号:
851729-48-1
分子量:
246.35
MDL编号:
MFCD18252680
UNSPSC代码:
12352100
PubChem化学物质编号:
329764639
NACRES:
NA.23

$195.00

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质量水平

100

方案

98% (HPLC)

表单

solid

mp

122-127 °C

SMILES字符串

CC(C)(SC(=S)c1ccc(cc1)C#N)C#N

InChI

1S/C12H10N2S2/c1-12(2,8-14)16-11(15)10-5-3-9(7-13)4-6-10/h3-6H,1-2H3

InChI key

GLQSCQVGVPUIPC-UHFFFAOYSA-N

相关类别

一般描述

需要帮助选择正确的可逆加成-断裂链转移剂? 请翻阅单体目录里面的RAFT部分兼容性表格.

应用

用于可控自由基聚合的可逆加成 - 断裂链转移剂;特别适合苯乙烯，丙烯酸酯和丙烯酰胺单体聚合。链转移剂（CTA）

法律信息

销售仅用于研究目的:请访问sigma-aldrich.com/raftlicense 专利: WO98/01478; WO99/311444

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H317

预防措施声明

P280

危险分类

Skin Sens. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCR4900
MKCJ5571
MKCF3762
MKCD1034
MKBV2748V

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

逆加成-断裂链转移 (RAFT)聚合

RAFT（可逆加成断裂链转移）聚合是一种可逆的去活化自由基聚合（RDRP），是给自由基聚合赋予活性的通用方法之一。

RAFT Polymerization

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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实验方案

RAFT聚合反应操作步骤

RAFT（可逆加成-断裂链转移）是一种活性自由基聚合反应，在有适合的连转移（RAFT）试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

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