700770

(R)-SIPHOS-PE

97%

• 别名: (11aR)-(+)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺, N-二[(R)-1-苯乙基]-[(R)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺
• 经验公式（希尔记法）: C₃₃H₃₂NO₂P
• CAS号: 500997-69-3
• 分子量: 505.59
• MDL编号: MFCD08459342
• UNSPSC代码: 12352005
• PubChem化学物质编号: 329762230

属性

• 方案: 97%
• 表单: powder
• 旋光性: [α]22/D +337°, c = 1 in chloroform
• mp: 90-96 °C
• 储存温度: −20°C
• InChI: 1S/C33H32NO2P/c1-23(25-11-5-3-6-12-25)34(24(2)26-13-7-4-8-14-26)37-35-29-17-9-15-27-19-21-33(31(27)29)22-20-28-16-10-18-30(36-37)32(28)33/h3-18,23-24H,19-22H2,1-2H3/t23-,24-,33?/m1/s1
• InChI key: ZXLQLIDJAURBDD-HRPAVAKOSA-N

说明

应用

(R)-SIPHOS-PE can be used as:

• A catalyst in the preparation of tricyclic alkaloid (+)-aphanorphine via asymmetric carboamination and Friedel−Crafts reaction.[1]
• A ligand in the synthesis of chiral ketones via hydroacylation of olefins using salicylaldehyde derivatives.[2]
• A ligand in the enantioselective synthesis of substituted pyrrolidine derivatives via Pd-catalyzed alkene aminoarylation reactions.[3]

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 储存分类代码: 13 - Non Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves