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69893

Sigma-Aldrich

2-吗啉代乙基异腈

≥98.0% (GC)

别名:

4-(2-异氰基乙基)吗啉, MEI

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10 ML
$216.00
50 ML
$1,030.00

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10 ML
$216.00
50 ML
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About This Item

经验公式（希尔记法）:
C7H12N2O
CAS号:
78375-48-1
分子量:
140.18
Beilstein:
4666990
MDL编号:
MFCD00040506
UNSPSC代码:
12352100
PubChem化学物质编号:
57652222
NACRES:
NA.22

$216.00

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质量水平

200

方案

≥98.0% (GC)

表单

liquid

折射率

n20/D 1.469

沸点

72-73 °C/0.7 mmHg (lit.)

密度

1.017 g/mL at 20 °C (lit.)

官能团

amine
ether
isonitrile

储存温度

−20°C

SMILES字符串

[C-]#[N+]CCN1CCOCC1

InChI

1S/C7H12N2O/c1-8-2-3-9-4-6-10-7-5-9/h2-7H2

InChI key

MFRZPLYKVDHOSN-UHFFFAOYSA-N

相关类别

应用

2-吗啉代乙基异腈可用于合成：
  • 氮无环卡宾(NAC)复合物，作为酚合成与炔烃水合的催化剂。[1]
  • 通过Ugi缩合反应形成各种咪唑并[1,2-a]吡啶[2]和α-酰氨基酰胺。[3]
  • 具有重要治疗价值的2-氨基苯并噁唑和3-氨基苯并噁嗪。[4]

它也用作有机发光二极管(OLED)用环金属铱配合物的配体。[5]

其他说明

多肽合成的强效偶联剂，与DCCI相比产率更高、消旋产物最少[6][7][8][9]；类Passerini 反应试剂，生成α-羟基酰胺[10]

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCH2510
BCCB6797
BCBV5100
BCBR4961V
BCBQ1832V

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Microwave-assisted solid-phase Ugi four-component condensations.
Hoel AML and Nielsen J
Tetrahedron Letters, 40(20), 3941-3944 (1999)
Michael J Kinney et al.
PloS one, 12(11), e0188660-e0188660 (2017-11-29)
Horizontal behavior of highly migratory marine species is difficult to decipher because animals are wide-ranging, spend minimal time at the ocean surface, and utilize remote habitats. Satellite telemetry enables researchers to track individual movements, but population level inferences are rare
Karen A Bjorndal et al.
Global change biology, 23(11), 4556-4568 (2017-04-06)
Somatic growth is an integrated, individual-based response to environmental conditions, especially in ectotherms. Growth dynamics of large, mobile animals are particularly useful as bio-indicators of environmental change at regional scales. We assembled growth rate data from throughout the West Atlantic
David Jakubosky et al.
Nature communications, 11(1), 2927-2927 (2020-06-12)
Structural variants (SVs) and short tandem repeats (STRs) comprise a broad group of diverse DNA variants which vastly differ in their sizes and distributions across the genome. Here, we identify genomic features of SV classes and STRs that are associated
New and Easily Accessible Nitrogen Acyclic Gold (I) Carbenes: Structure and Application in the Gold-Catalyzed Phenol Synthesis as well as the Hydration of Alkynes.
Hashmi ASK, et al.
Advanced Synthesis & Catalysis, 352(8), 1315-1337 (2010)
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