692336

RuCl₂[(R)-(DM-SEGPHOS^®)][(R,(R))-(DPEN)]

• 别名: 二氯[(R)-5,5′-双[二(3,5-二甲苯基)膦]-4,4′-二-1,3-苯并二噁茂][(1R,2R)-1,2-二苯基乙二胺]钌(II)
• 经验公式（希尔记法）: C₆₀H₆₀Cl₂N₂O₄P₂Ru
• CAS号: 944450-45-7
• 分子量: 1107.05
• MDL號碼: MFCD09753031
• 分類程式碼代碼: 12352005
• PubChem物質ID: 329761484
• NACRES: NA.22

属性

• 形狀: powder
• 儲存溫度: 2-8°C
• SMILES 字串: Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
• InChI: 1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
• InChI 密鑰: FOEKPXQPRAIJRW-ODQAEMFESA-L

说明

應用

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl₂[(R)-(DM-SEGPHOS^®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.

法律資訊

与 Takasago 合作销售，仅用于研究目的。日本注册号 3148136，日本申请号 19970359654

SEGPHOS is a registered trademark of Takasago Intl. Corp.

安全信息

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable