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Merck
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文件

680990

Sigma-Aldrich

1,1′-双[(2R,5R)-2,5-二乙基膦烷基]二茂铁

别名:

R,R-Et-Ferrocelane™

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About This Item

经验公式（希尔记法）:
C26H40FeP2
CAS号:
147762-89-8
分子量:
470.39
分類程式碼代碼:
12352005
PubChem物質ID:
24885607
NACRES:
NA.22

形狀

solid

光學活性

[α]20/D +380°, c = 1 in chloroform

mp

85-91 °C

SMILES 字串

C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4

InChI

1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1

InChI 密鑰

CPUKIDAUDCWIRT-QULUYMGFSA-N

相关类别

應用

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:
  • As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
  • As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.

法律資訊

与 Kanata Chemical Technologies Inc. 联合销售，仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售，此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

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Highly efficient asymmetric hydrogenation of 2-Methylenesuccinamic acid using a Rh-DuPHOS catalyst
Cobley CJ, et al.
Organic Process Research & Development, 7(3), 407-411 (2003)
New chiral 1, 1′-bis (phospholano) ferrocene ligands for asymmetric catalysis
Burk MJ and Gross MF
Tetrahedron Letters, 35(50), 9363-9366 (1994)

商品

DuPhos and BPE Ligands

Asymmetric hydrogenation enables scalable synthesis of single-enantiomer compounds with minimal byproducts, ideal for commercial manufacturing.

相关内容

DuPhos and BPE Ligands

Asymmetric hydrogenation reactions represent the ideal process for the commercial manufacture of single-enantiomer compounds, because of the ease by which these robust procedures can be scaled up and because of the low levels of byproducts generated in these asymmetric hydrogenations.

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