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Merck

669164

Sigma-Aldrich

(N-Boc-2-吡咯基)二甲基硅烷醇

97%

别名:

N-Boc-2-(羟基二甲基硅基)吡咯

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About This Item

线性分子式:
((CH3)3COC(O))(C4H3N)(Si(CH3)2(OH))
分子量:
241.36
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

mp

48-57 °C

儲存溫度

2-8°C

SMILES 字串

CC(C)(C)OC(=O)n1cccc1[Si](C)(C)O

InChI

1S/C11H19NO3Si/c1-11(2,3)15-10(13)12-8-6-7-9(12)16(4,5)14/h6-8,14H,1-5H3

InChI 密鑰

RLDVDBYGGISJNL-UHFFFAOYSA-N

應用

(N-Boc-2-pyrrolyl)dimethylsilanol can be used as a substrate:
  • To prepare cross-coupling products by reacting with various aryl iodides.[1][2]
  • In the synthesis of alkoxyhydrosiloxanes by reacting with alkoxyhydrosilanes.[3]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

A catalyst-and additive-free synthesis of alkoxyhydrosiloxanes from silanols and alkoxyhydrosilanes
Satoh Y, et al.
Chemical Communications (Cambridge, England), 56(59), 8218-8221 (2020)
Organosilicon Chemistry
Denmark SE and Baird JD
Aldrich Chemfiles, 6(5), 1-14 (2006)
Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides
Denmark SE and Baird JD
Organic Letters, 8(4), 793-795 (2006)
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

商品

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

相关内容

Over the past several years, the Pd-catalyzed cross-coupling of silicon compounds (Hiyama coupling) has rapidly gained acceptance as a suitable alternative to more commonly used methods such as Stille (Sn), Kumada (Mg), Suzuki (B), and Negishi cross-couplings (Zn).

Over the past several years, Pd-catalyzed cross-coupling of silicon compounds has rapidly gained acceptance as a suitable alternative to more commonly known methods such as: Stille (Sn), Kumada (Mg), Suzuki (B), and Negishi (Zn) cross-couplings.

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