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666335

Pd EnCat^® 套装 I

Name: Pd EnCat<SUP>®</SUP> 套装 I
Brand: ALDRICH

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About This Item

分類程式碼代碼:

12352300

NACRES:

NA.22

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

應用

Catalysis Screening Kits

A kit of 5 Pd EnCat^® catalysts which are micro-encapsulated palladium acetate catalysts with or without phosphine ligands which facilitate carbon-carbon bond forming processes as well as the removal of palladium metal contamination.

法律資訊

EnCat is a registered trademark of Reaxa Ltd.

试剂盒组分也可单独购买

产品编号

说明

化学品安全说明书

644692Pd EnCat^® TOTP30, extent of labeling: 0.4 mmol/g Pd loading, TOTP 0.5, Pd 1.0 1 g化学品安全说明书

644706Pd EnCat^® TPP30, extent of labeling: 0.4 mmol/g Pd loading, TPP 0.8, Pd 1.0 1 g化学品安全说明书

644714Pd EnCat^® 30, extent of labeling: 0.4 mmol/g Pd loading 1 g化学品安全说明书

644722Pd EnCat^® 40, extent of labeling: 0.4 mmol/g Pd loading 1 g化学品安全说明书

658693Pd(II) EnCat^® BINAP30, extent of labeling: 0.39 mmol/g Pd loading, BINAP 0.25, Pd 1.0 1 g化学品安全说明书

象形圖

GHS02,GHS08,GHS07

訊號詞

Danger

危險聲明

H228,H315,H319,H351,H360Df,H373,H412

防範說明

P202 - P210 - P273 - P302 + P352 - P305 + P351 + P338 - P308 + P313

危險分類

Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Sol. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT RE 2 Oral

標靶器官

Liver,Kidney, Nervous system

儲存類別代碼

4.1B - Flammable solid hazardous materials

閃點（°F）

-9.4 - -7.6 °F

閃點（°C）

-23 - -22 °C

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Transfer hydrogenation using recyclable polyurea-encapsulated palladium: efficient and chemoselective reduction of aryl ketones.

Jin-Quan Yu et al.

Chemical communications (Cambridge, England), (6), 678-679 (2003-04-22)

A robust and recyclable palladium catalyst [Pd0EnCat] has been prepared by ligand exchange of polyurea-encapsulated palladium(II) acetate with formic acid, resulting in deposition of Pd(0) in the support material; Pd0EnCat is shown to be a highly efficient transfer hydrogenation catalyst

Recyclable polyurea-microencapsulated Pd(0) nanoparticles: an efficient catalyst for hydrogenolysis of epoxides.

Steven V Ley et al.

Organic letters, 5(24), 4665-4668 (2003-11-25)

[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.

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