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665479

Sigma-Aldrich

(S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a′]二萘-4-基)哌啶

97%

别名:

(S)-(+)-4-二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-基-哌啶, (S)-PipPhos

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About This Item

经验公式（希尔记法）:
C25H22NO2P
分子量:
399.42
MDL號碼:
MFCD08276865
分類程式碼代碼:
12352005
PubChem物質ID:
24884739

化驗

97%

形狀

solid

mp

206-213 °C

SMILES 字串

C1CCN(CC1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56

InChI

1S/C25H22NO2P/c1-6-16-26(17-7-1)29-27-22-14-12-18-8-2-4-10-20(18)24(22)25-21-11-5-3-9-19(21)13-15-23(25)28-29/h2-5,8-15H,1,6-7,16-17H2

InChI 密鑰

ZYDGLCZCEANEHK-UHFFFAOYSA-N

應用

N-芳基亚胺的不对称氢化反应
亚磷酰胺配体，用于芳基硼酸经铑催化的不对称 1,4-加成反应，加成到 α,β-不饱和羰基化合物。
DSM MonoPhos Family of Highly Efficient Privileged Ligands

法律資訊

经 DSM 授权销售，仅供研究使用。

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
01203CE

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Natasa Mrsić et al.
Journal of the American Chemical Society, 131(24), 8358-8359 (2009-06-18)
Asymmetric hydrogenation of N-aryl acetophenone imines using iridium/PipPhos leads to very high enantioselectivities up to >99% depending on the presence of electron-donating substituents in the 2-, 3-, and 5-position of the aryl ring. If the substituent is 2-methoxy, the resultant
Journal of Organometallic Chemistry, 692, 428-428 (2007)

商品

DSM MonoPhos™ Ligands

DSM collaboration offers MonoPhos™ ligands for research, based on the BINOL platform by Feringa and co-workers.

相关内容

DSM MonoPhos™ Ligands

In collaboration with DSM, we are pleased to offer a range of MonoPhos™ ligands for the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate phosphoramidites based on the privileged BINOL platform.

DSM MonoPhos Family

A diverse array of these chiral, monodentate phosphoramidites based on the privileged BINOL platform. The MonoPhos™ family has exhibited high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed asymmetric 1,4-additions of organometallic reagents to allylic alkylations to desymmetrization of meso-cycloalkene oxides.

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