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665355

Sigma-Aldrich

(S)-(+)-苄基(3,5-二氧杂-4-磷杂-环庚[2,1-a;3,4-a′]二萘-4-基)甲胺

97%

别名:

(+)-N-苄基-N-甲基-二萘并[2,1-d:1′,2′]二噁磷杂庚英-4-胺，(11bS)

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100 MG
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100 MG
$99.70

About This Item

经验公式（希尔记法）:
C28H22NO2P
CAS号:
490023-37-5
分子量:
435.45
MDL编号:
MFCD04117686
UNSPSC代码:
12352005
PubChem化学物质编号:
24884732
NACRES:
NA.22

$99.70

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质量水平

100

方案

97%

表单

solid

mp

155-159 °C

SMILES字符串

CN(Cc1ccccc1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56

InChI

1S/C28H22NO2P/c1-29(19-20-9-3-2-4-10-20)32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-18H,19H2,1H3

InChI key

OHGGHRJGBXAKKY-UHFFFAOYSA-N

相关类别

应用

用作芳基硼酸经铑催化不对称 1,4-加成到 α,β-不饱和羰基化合物的亚磷酰胺配体。[1]还用于N-酰化 β-脱氢氨基酯的不对称氢化，生成对映纯 β-氨基酸衍生物。[2]
DSM MonoPhos Family of Highly Efficient Privileged Ligands

法律信息

经 DSM 授权销售，仅供研究之用。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
01503CE

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Diego Peña et al.
Journal of the American Chemical Society, 124(49), 14552-14553 (2002-12-06)
New and very easily accessible monodentate phosphoramidite ligands have been developed that lead to excellent ee's and full conversions in the hydrogenation of (E)- and (Z)-beta-dehydroamino acid derivatives with both aliphatic and aromatic side chains. Particularly, two different catalytic systems
Journal of Organometallic Chemistry, 692, 428-428 (2007)

商品

DSM MonoPhos™ Ligands

DSM collaboration offers MonoPhos™ ligands for research, based on the BINOL platform by Feringa and co-workers.

相关内容

DSM MonoPhos™ Ligands

In collaboration with DSM, we are pleased to offer a range of MonoPhos™ ligands for the research market.† Feringa and co-workers have invented a diverse array of these chiral, monodentate phosphoramidites based on the privileged BINOL platform.

DSM MonoPhos Family

A diverse array of these chiral, monodentate phosphoramidites based on the privileged BINOL platform. The MonoPhos™ family has exhibited high levels of enantiocontrol in synthetic transformations ranging from metal-catalyzed asymmetric 1,4-additions of organometallic reagents to allylic alkylations to desymmetrization of meso-cycloalkene oxides.

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