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Merck

549797

Sigma-Aldrich

丙烯酰氯

97.0%, contains <210 ppm MEHQ as stabilizer

别名:

2-丙烯酰氯

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About This Item

线性分子式:
CH2=CHCOCl
CAS号:
分子量:
90.51
Beilstein:
635744
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
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蒸汽密度

>1 (vs air)

质量水平

蒸汽压

1.93 psi ( 20 °C)

方案

97.0%

包含

<210 ppm MEHQ as stabilizer

折射率

n20/D 1.435 (lit.)

沸点

72-76 °C (lit.)

密度

1.114 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

ClC(=O)C=C

InChI

1S/C3H3ClO/c1-2-3(4)5/h2H,1H2

InChI key

HFBMWMNUJJDEQZ-UHFFFAOYSA-N

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一般描述

丙烯酰氯是丙烯酸的衍生物,广泛用作反应单体,用于合成具有良好透明度、柔韧性、优异机械和热学性能以及耐潮湿和耐化学品等性能的各种聚合物。丙烯酰氯的结构中含有一个丙烯酰基(-CH2=CHC(O)Cl)和氯官能团(-Cl)。这种官能团的组合使丙烯酰氯能够进行聚合瓜并参与共聚合过程。在聚合物领域,丙烯酰氯常用于生产丙烯酸聚合物,如聚丙烯酸酯和聚甲基丙烯酸酯。这些聚合物具有广泛的应用,包括涂料、胶粘剂、密封剂、纺织品和生物医学材料。

应用

丙烯酰氯可作为单体用于:
  • 通过自由基聚合或共聚合合成丙烯酸聚合物。这些丙烯酸聚合物可进行定制,以具备生物医学涂层所需要性能,包括生物相容性、与设备表面的粘附性和耐久性。
  • 通过与苯乙烯交联合成苯乙烯-共丙烯酰氯共聚物。然后,通过各种化学反应对所得到的交联聚合物进行官能化或修饰,以引入特定性质或功能,以用作聚合物载体或亲电清除树脂。
  • 丙烯酰胺修饰的壳聚糖。
  • 通过多糖羟基酯化制备丙烯酸酯大分子单体。这种大分子单体可用于制备石莼基热敏水凝胶。
  • 作为可降解多肽交联剂,通过丙烯酰化与多肽序列中赖氨酸残基中的氨基和谷氨酰胺反应。

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

30.2 °F

闪点(°C)

-1 °C


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Andrea Morelli et al.
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The present study is focused on the exploitation and conversion of sulphated polysaccharides obtained from waste algal biomass into high value added material for biomedical applications. ulvan, a sulphated polysaccharide extracted from green seaweeds belonging to Ulva sp. was selected
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Hydrogels composed of N-isopropylacrylamide (NIPAAm) and acrylic acid (AAc) were prepared by redox polymerization with peptide cross-linkers to create an artificial extracellular matrix (ECM) amenable for testing hypotheses regarding cell proliferation and migration in three dimensions. Peptide degradable cross-linkers were
Jung Im Lee et al.
International journal of pharmaceutics, 373(1-2), 93-99 (2009-05-12)
Chitosan/Pluronic hydrogels were prepared to develop injectable depot systems for gene therapy to enhance local transgene expression at injection sites. Water-soluble chitosan and Pluronic were separately acrylated to prepare photo-crosslinkable polymers. A mixture of acrylated polymers was mixed with plasmid
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Analytical chemistry, 77(3), 772-779 (2005-02-01)
We have created a family of water-soluble block copolymers of acrylamide and N-alkylacrylamides that are designed to selectively remove proteins from DNA via microchannel electrophoresis. It was hypothesized that the inclusion of hydrophobic subunits in the polymer chain, in sufficient
Iris Ben-David et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 58(2), 209-217 (2003-02-08)
An automated procedure for the radiosynthesis of the labeling synthon [11C]acryloyl chloride was developed and applied for labeling several N-acryl amides with carbon-11. [11C]-6-acrylamido-4-(3,4-dichloro-6-fluoroanilino)quinazoline (ML03), a novel PET biomarker targeting the epidermal growth factor receptor tyrosine kinase (EGFr-TK) in cancer

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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