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Merck

538264

Sigma-Aldrich

丁腈

≥99%

别名:

丙基氰

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100 ML
$100.00
1 L
$288.00

About This Item

线性分子式:
CH3CH2CH2CN
CAS号:
分子量:
69.11
Beilstein:
1361452
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$100.00


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蒸汽密度

2.4 (vs air)

质量水平

蒸汽压

23 mmHg ( 25 °C)

方案

≥99%

自燃温度

910 °F

折射率

n20/D 1.384 (lit.)

沸点

115-117 °C (lit.)

mp

−112 °C (lit.)

溶解性

DMF: miscible(lit.)
alcohol: miscible(lit.)
diethyl ether: miscible(lit.)
water: very slightly soluble(lit.)

密度

0.794 g/mL at 25 °C (lit.)

官能团

nitrile

SMILES字符串

CCCC#N

InChI

1S/C4H7N/c1-2-3-4-5/h2-3H2,1H3

InChI key

KVNRLNFWIYMESJ-UHFFFAOYSA-N

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一般描述

丁腈(丙腈,BN)是一种线性氰化物。采用气相沉积法制备了丁腈 (BN) 玻璃。研究了氮化硼玻璃的摩尔体积与沉积温度的关系。[1]其与高温水(温度 = 330℃,压力范围 = 128-2600 bar)反应生成丁酰胺、丁酸和氨。[2]在 LiOH 促进的钴基 Raney 催化剂存在下发生选择性还原,得到 n -丁胺。[3]

应用

丁腈适合用于研究立体化学因素对价间电荷转移 (IT) 的影响。[4]它可用于染料敏化太阳能电池的电解质组成。[5]

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

71.6 °F

闪点(°C)

22 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Slide 1 of 1

1 of 1

Tailoring Raney-catalysts for the selective hydrogenation of butyronitrile to n-butylamine.
Chojecki A, et al.
J. Catal., 245(1), 237-248 (2007)
Stereochemical influences on intervalence charge transfer in homodinuclear complexes of ruthenium.
D M D'Alessandro et al.
Inorganic chemistry, 40(26), 6841-6844 (2001-12-12)
Hideyuki Nakayama et al.
The journal of physical chemistry. B, 117(35), 10311-10319 (2013-08-08)
Molar volumes (Vm) of vapor-deposited ethylcyclohexane (ECH) and butyronitrile (BN, sometimes called butanenitrile) glasses were studied as a function of deposition temperature (Td). ECH glasses deposited at Td sufficiently below their glass-transition temperature (Tg) exhibited changes in Vm on heating
Frédéric Sauvage et al.
Journal of the American Chemical Society, 133(33), 13103-13109 (2011-06-28)
We elaborated a new electrolyte composition, based on butyronitrile solvent, that exhibits low volatility for use in dye-sensitized solar cells. The strong point of this new class of electrolyte is that it combines high efficiency and excellent stability properties, while
Effect of pressure on the rate of butyronitrile hydrolysis in high-temperature water.
Iyer SD and Klein MT.
Journal of Supercritical Fluids, 10(3), 191-200 (1997)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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