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About This Item
经验公式（希尔记法）:
C10H14O5
CAS号:
分子量:
214.22
Beilstein:
5338165
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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方案
96%
旋光性
[α]20/D −10°, c = 1 in methanol
mp
102-105 °C (lit.)
SMILES字符串
OC1OC(=O)[C@@H]2OC3(CCCCC3)O[C@H]12
InChI
1S/C10H14O5/c11-8-6-7(9(12)13-8)15-10(14-6)4-2-1-3-5-10/h6-8,11H,1-5H2/t6-,7+,8?/m0/s1
InChI key
GHGRKHAVPBZSIH-KJFJCRTCSA-N
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应用
(+)-2,3-Cyclohexylidene-L-erythruronic acid can be used as a starting material to prepare (2R,3S)-1,4-bis(diphenylphosphino)butane-2,3-diol ligand, which is further used to synthesize Rh(I) based catalyst for the hydrogenation of olefins.[1]
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Cooperative attractive interactions in asymmetric hydrogenations with dihydroxydiphosphine Rh (I) catalysts-a competition study
Holz J, et al.
Journal of Organometallic Chemistry, 603(1), 61-68 (2000)
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