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Merck
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520810

Sigma-Aldrich

钯黑

greener alternative

99.95% trace metals basis

别名:

沉淀钯

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About This Item

经验公式（希尔记法）:
Pd
CAS号:
7440-05-3
分子量:
106.42
EC 号:
231-115-6
MDL编号:
MFCD00011167
UNSPSC代码:
12161600
PubChem化学物质编号:
24874171
NACRES:
NA.22

方案

99.95% trace metals basis

表单

solid

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

表面积

40-60 m2/g

环保替代产品分类

Enabling,

SMILES字符串

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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一般描述

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了能源效率。点击此处，查看更多详情。

应用

钯黑（以痕量金属计纯度为99.95％）可用作多种可持续应用中的催化剂，其表面积高，约为47 m2g−1。[1]它可用作具有良好性能的阳极催化剂，并可用于聚合物交换膜（PEM）燃料电池。[2]它也可用作氢解反应中钯炭催化剂的替代催化剂。[3]

象形图

FlameExclamation mark
GHS02,GHS07

警示用语：

Danger

危险分类

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBX5362V
MKBQ4182V
MKBG9360V
MKBB5927
74598MJ

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Freestanding palladium nanosheets with plasmonic and catalytic properties
Huang X, et al.
Nature Nanotechnology, 6(1), 28-28 (2011)
Palladium black as model catalyst in the hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32)
Van de Sandt E, et al.
Applied Catalysis A: General, 155(1), 59-73 (1997)
The behavior of palladium catalysts in direct formic acid fuel cells
Zhu Y, et al.
Journal of Power Sources, 139(1-2), 15-20 (2005)
Stefano Nicolai et al.
The Journal of organic chemistry, 78(8), 3783-3801 (2013-03-21)
Tetrahydrofurans and pyrrolidines are among the most important heterocycles found in bioactive compounds. Cyclization-functionalization domino reactions of alcohols or amines onto olefins constitute one of the most efficient methods to access them. In this context, oxy- and aminoalkynylation are especially
Meng Wang et al.
Organic & biomolecular chemistry, 11(16), 2574-2577 (2013-03-15)
A novel Pd/Cu catalyzed domino reaction for the synthesis of functionalized pyrrolo[1,2-b]pyridazines from readily accessible (hetero)aryl propargyl alcohols and 1-amino-2-bromopyrroles was developed. This cascade process involves a Sonogashira cross-coupling reaction, an isomerization and an intramolecular condensation.
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