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Merck

510459

Sigma-Aldrich

2,6-二氯碘苯

98%

别名:

1,3-二氯-2-碘苯

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About This Item

线性分子式:
Cl2C6H3I
CAS号:
分子量:
272.90
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
化驗:
98%

化驗

98%

mp

64-67 °C (lit.)

SMILES 字串

Clc1cccc(Cl)c1I

InChI

1S/C6H3Cl2I/c7-4-2-1-3-5(8)6(4)9/h1-3H

InChI 密鑰

ZMPGXSFTXBOKFM-UHFFFAOYSA-N

一般說明

2,6-Dichloroiodobenzene, also known as 1,3-dichloro-2-iodobenzene, is a halo-substituted benzene. It couples with 1,1′-diaminoferrocene in the presence of a palladium catalyst to form substituted diamide ligands (Fc(NHAr)2).[1]

應用

2,6-Dichloroiodobenzene may be used in the preparation of 2,6-dichlorobenzo[14C]nitrile[2] and 2,6-terphenyl carboxylic acid ligands.[3]
It may be used as a starting material in the multi-step synthesis of:
  • cupped oxacyclophanes[4]
  • cuppedophanes[5]
  • cappedophanes[5]
  • m-terphenyls[6]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Non-interconvertible conformers of cupped oxacyclophanes.
Grewal RS and Hart H.
Tetrahedron Letters, 31(30), 4271-4274 (1990)
Encapsulation of the uranyl dication.
Beer S, et al.
Chemical Science, 1(1), 43-47 (2010)
Zirconium complexes incorporating diaryldiamidoferrocene ligands: generation of cationic derivatives and polymerization activity towards ethylene and 1-hexene.
Shafir A and Arnold J.
Inorgorganica Chimica Acta, 345, 216-220 (2003)
Oxacyclophanes based on a m-terphenyl framework.
Grewal RS, et al.
The Journal of Organic Chemistry, 57(9), 2721-2726 (1992)
M H Griffiths et al.
The Biochemical journal, 98(3), 770-781 (1966-03-01)
1. A single oral dose of either [(14)C]Prefix or 2,6-dichlorobenzo[(14)C]nitrile to rats is almost entirely eliminated in 4 days: 84.8-100.5% of (14)C from [(14)C]Prefix is excreted, 67.3-79.7% in the urine, and 85.8-97.2% of (14)C from 2,6-dichlorobenzo-[(14)C]nitrile is excreted, 72.3-80.7% in

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