498041

环戊基溴化锌 溶液

0.5 M in THF

• 别名: Bromo(cyclopentyl)zinc, Bromocyclopentylzinc
• 线性分子式: C₅H₉ZnBr
• CAS号: 171860-68-7
• 分子量: 214.42
• MDL编号: MFCD00671991
• UNSPSC代码: 12352103
• PubChem化学物质编号: 24873166
• NACRES: NA.22

属性

• 质量水平: 100
• 浓度: 0.5 M in THF
• 密度: 0.955 g/mL at 25 °C
• 储存温度: 2-8°C
• SMILES字符串: Br[Zn]C1CCCC1
• InChI: 1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1
• InChI key: GOPYCBPMCCJYSN-UHFFFAOYSA-M

说明

应用

Cyclopentylzinc bromide is an organozinc reagent that can be used in:

• The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.[1]
• Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.[2]
• The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.[3]

法律信息

Rieke® Metals, Inc. 制造。®Rieke Metals, Inc. 的注册商标。

安全信息

• 象形图: GHS02,GHS08,GHS07
• 警示用语：: Danger
• 危险声明: H225,H261,H302,H315,H319,H335,H351
• 预防措施声明: P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
• 危险分类: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
• 靶器官: Respiratory system
• 补充剂危害: EUH019
• 储存分类代码: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 闪点(°F): 1.4 °F - closed cup
• 闪点(°C): -17 °C - closed cup