481718

五羰基铁

>99.99% trace metals basis

• 别名: 五羰基铁, 羰基铁
• 线性分子式: Fe(CO)₅
• CAS号: 13463-40-6
• 分子量: 195.90
• EC 号: 236-670-8
• MDL编号: MFCD00011001
• UNSPSC代码: 12352103
• PubChem化学物质编号: 24871777
• NACRES: NA.23

属性

• 蒸汽密度: 6.74 (vs air)
• 质量水平: 100
• 蒸汽压: 35 mmHg ( 25 °C); 40 mmHg ( 30.3 °C)
• 方案: >99.99% trace metals basis
• 表单: liquid
• 自燃温度: 122 °F
• 反应适用性: core: iron; reagent type: catalyst
• 环保替代产品特性: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• 折射率: n20/D 1.5196 (lit.)
• 沸点: 103 °C (lit.)
• mp: −20 °C (lit.)
• 密度: 1.49 g/mL at 25 °C (lit.)
• 环保替代产品分类: , Aligned
• 储存温度: 2-8°C
• SMILES字符串: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/5CO.Fe/c5*1-2;
• InChI key: FYOFOKCECDGJBF-UHFFFAOYSA-N

说明

一般描述

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

用作以下过程的反应物：

• 加成反应
• 通过光解分解
• 热分解法制备尺寸分布窄的铁洋葱状富勒烯磁性微粒
• 碳酰胺氢硅烷还原反应中七核铁羰基簇合物的制备

• 高碱性条件下制备光催化析氢 Fe 纳米粒子的前驱体

Chemical Synthesis of Monodisperse Magnetic Nanoparticles

Iron(0) pentacarbonyl can be used:

• To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
• As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
• To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

安全信息

• 象形图: GHS02,GHS06
• 警示用语：: Danger
• 危险声明: H225,H300 + H330,H311
• 预防措施声明: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P304 + P340 + P310
• 危险分类: Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2
• 储存分类代码: 3 - Flammable liquids
• WGK: WGK 1
• 闪点(°F): 5.0 °F - closed cup
• 闪点(°C): -15 °C - closed cup
• 个人防护装备: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter