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Merck

479152

Sigma-Aldrich

4-溴苄胺

96%

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About This Item

线性分子式:
BrC6H4CH2NH2
CAS号:
分子量:
186.05
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

96%

bp

110-112 °C/30 mmHg (lit.)

mp

25 °C (lit.)

密度

1.473 g/mL at 25 °C (lit.)

SMILES 字串

NCc1ccc(Br)cc1

InChI

1S/C7H8BrN/c8-7-3-1-6(5-9)2-4-7/h1-4H,5,9H2

InChI 密鑰

XRNVSPDQTPVECU-UHFFFAOYSA-N

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一般說明

4-溴苄胺(BBA)又名 p-溴苄胺,是一种芳基溴化物。据报道,在存在红铜的条件下,其可由BBA选择性地形成腈或亚胺。 BBA形成2,6,9-三氮杂双环[3.3.1]壬烷衍生物的formal[4 + 4]反应已有研究。

應用

4-溴苄胺(p-溴苄胺)可用于合成7-[(p-溴苄基)脲基]-7,8-二氢-α-双丁二烯。
它可用于合成以下4-联苯甲胺衍生物:
  • (4′-氟-4-联苯)甲胺
  • (4′-甲氧基-4-联苯)甲胺
  • (2′-甲氧基-4-联苯)甲胺
  • (3′-氰基-4-联苯)甲胺

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

>230.0 °F - closed cup

閃點(°C)

> 110 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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We developed a new method for modifying the side chains of peptoids on a solid phase resin, employing the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. Optimized conditions using Pd(PPh3 )4 and K2 CO3 in the presence of Buchwald's SPhos ligand provided a

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