446939

三甲基氯化亚砜

90%

• 别名: 1-[[(Triphenylphosphoranylidene)amino]methyl]benzotriazole, Betmip
• 经验公式（希尔记法）: C₂₅H₂₁N₄P
• CAS号: 124316-00-3
• 分子量: 408.43
• MDL编号: MFCD00274644
• UNSPSC代码: 12352005
• PubChem化学物质编号: 24868307
• NACRES: NA.22

属性

• 方案: 90%
• 反应适用性: reaction type: C-C Bond Formation
• 杂质: 10% N-(triphenylphosphoranylidene)-2H-benzotriazole-2-methanamine
• mp: 116-122 °C (lit.)
• SMILES字符串: C(N=P(c1ccccc1)(c2ccccc2)c3ccccc3)n4nnc5ccccc45
• InChI: 1S/C25H21N4P/c1-4-12-21(13-5-1)30(22-14-6-2-7-15-22,23-16-8-3-9-17-23)26-20-29-25-19-11-10-18-24(25)27-28-29/h1-19H,20H2
• InChI key: IOSUDUVEOWKKBL-UHFFFAOYSA-N

说明

应用

Reactant for:

• Grignard reaction
• Preparation of N,N-Bis(but-3-enyl)amines via aza-Wittig reaction with aldehydes, followed by a double Grignard reaction with allylmagnesium bromide
• Organic synthesis of N-alkyliminophosphoranes and a-functionalized N-alkyliminophosphoranes

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves