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Merck

440167

Sigma-Aldrich

(3--缩水甘油丙氧基)三甲氧基硅烷

≥98%

别名:

Dow Corning® 产品 Z-6040, γ-缩水甘油醚氧丙基三甲氧基硅烷, 3-甘油丙基三甲氧基硅烷, GLYMO

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100 ML
$110.00
500 ML
$362.00
1 L
$601.00
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$1,210.00

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100 ML
$110.00
500 ML
$362.00
1 L
$601.00
2.5 L
$1,210.00

About This Item

经验公式(希尔记法):
C9H20O5Si
CAS号:
分子量:
236.34
Beilstein:
4308125
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

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品質等級

化驗

≥98%

形狀

liquid

折射率

n20/D 1.429 (lit.)

bp

120 °C/2 mmHg (lit.)

密度

1.07 g/mL at 25 °C (lit.)

SMILES 字串

CO[Si](CCCOCC1CO1)(OC)OC

InChI

1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3

InChI 密鑰

BPSIOYPQMFLKFR-UHFFFAOYSA-N

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一般說明

(3-缩水甘油基氧基丙基)三甲氧基硅烷(GPTMS)是一种双官能团有机硅烷,其一侧有三个甲氧基,另一侧有环氧环。甲氧基与玻璃基材结合紧密,从而形成了一种3D基质。环氧基可与酰胺、醇、硫醇和酸发生反应。GPTMS在水中具有很高的反应活性,可以用作二氧化硅表面和聚合物基质之间的连接剂。[1][2][3]

應用

GPTMS是一种广泛使用的二氧化硅前体。GPTMS与正硅酸四乙酯(TEOS)可以与壳聚糖共混,用作骨组织工程聚合物骨架的填充剂。[4]它也可以涂覆在铝合金表面以防止腐蚀。 [5] GPTMS可用于对可用作环氧树脂基质纳米复合材料的增强材料的多壁碳纳米管(MWCNT)进行功能化修饰(包裹)。[2]
用(3-缩水甘油基氧基丙基)三甲氧基硅烷(GPTMS)对碳钢进行预处理可提高干态和湿态附着力,同时降低环氧涂层的阴极剥离率。[6]

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Aquatic Chronic 3 - Eye Dam. 1

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Functionalization of carbon nanotubes with (3-glycidyloxypropyl)-trimethoxysilane: Effect of wrapping on epoxy matrix nanocomposites.
Hoepfner, et al.
Journal of Applied Polymer Science, 133(47), 814-820 (2016)
An assessment of the corrosion protection of AA2024-T3 treated with vinyltrimethoxysilane/(3-glycidyloxypropyl) trimethoxysilane.
Dalmoro V et al.
Corrosion Science, 92(19), 200-208 (2015)
Ngoc-Hanh Cao-Luu et al.
Journal of colloid and interface science, 536, 536-547 (2018-11-06)
How to encapsulate poly(N-isopropylacrylamide) (PNIPAM) mesoglobule cores by silica shells greatly affects the resultant nanoparticle structures. Incorporation of acrylamide (AM) unit into PNIPAM in combination with 3-glycidyloxypropyltrimethoxysilane (GLYMO, as a coupling agent) effectively induces nucleation and growth of silica on
Giulia Giuntoli et al.
Frontiers in bioengineering and biotechnology, 8, 589223-589223 (2021-02-09)
Abdominal hernia repair is a frequently performed surgical procedure worldwide. Currently, the use of polypropylene (PP) surgical meshes for the repair of abdominal hernias constitutes the primary surgical approach, being widely accepted as superior to primary suture repair. Surgical meshes
Organic-inorganic bonding in chitosan-silica hybrid networks: physical properties.
Trujillo, et al.
Journal of Polymer Science. Part B, Polymer Physics, 53(19), 1391-1400 (2015)

商品

Hybrid organic-inorganic sol-gel materials containing silica were first called “ORMOSILs” in 1984.

Questions

1–9 of 9 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. I would like to know the solvent for GPTMS. What solvents does GPTMS dispersed in?

    1 answer
    1. This product is supplied as a neat or pure liquid with a density of 1.07 g/mL. The minimum purity is 98%. This compound is soluble in water, alcohols, acetone, and most aliphatic esters at normal application levels of 45%.

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  4. I connected  GPTMS synthetically to my lipid(APTES), now my lipid cannot be dissolved in chloroform, ethanol and methanol solutions, which was previously dissolved, what solvent should I use?

    1 answer
    1. The solubility of the GPTMS/APTES sample has not been tested, however decreasing the concentration in chloroform may be useful. Other solvents such as oils (see C8267) or a strong base, such as sodium hydroxide, may also be an option. See the link below to a publication that may be of interest:
      https://pubs.acs.org/doi/10.1021/acssuschemeng.9b06741

      If you have any further issues, please contact https://www.sigmaaldrich.com/techservice, click on "Product Technical Inquiries" under the Products Section, and provide the required information so that a member of the Technical Service team can reach out to assist further. Thank you.

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  5. What is the viscosity of Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO?

    1 answer
    1. This material is a low viscosity liquid with an average value of about 3 centistokes. Please note that this value is not part of our specifications.

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  6. Is Product 440167 (3-Glycidyloxypropyl)trimethoxysilane GLYMO, equivalent to Dow's Z-6040?

    1 answer
    1. Yes. This listing is manufactured by Dow Corning Corporation and distributed by Sigma-Aldrich.

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  7. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  8. What can Product 440167, 3-Glycidyloxypropyl)trimethoxysilane GLYMO, be used for?

    1 answer
    1. According to Dow Corning®, 3-GLYCIDOXYPROPYLTRIMETHOXYSILANE can be used as a coupling agent for many thermoset resins with glass or  mineral fillers. Specifically, it has been used as a reinforcement treatment on glass fiber to improve physical properties (especially wet strength) or as  an adhesion promoter to improve the bonding of a polymer coating or adhesive to glass, metals or other polymeric surfaces.

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  9. Where can I find more detailed information about how to use Product 440167. 3-Glycidyloxypropyl)trimethoxysilane, GLYMO, in adhesion/reinforcement applications?

    1 answer
    1. Dow Corning® has published a technical bulletin on this product, which is available by calling Technical Service at 800-231-8327.

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