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Merck

436011

Sigma-Aldrich

磷酸铁(III) 二水合物

Fe 29 %

别名:

二水磷酸铁

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250 G
$117.00
1 KG
$298.00

$117.00


国内现货,预计发货时间2025年4月07日详情


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250 G
$117.00
1 KG
$298.00

About This Item

线性分子式:
FePO4 · 2H2O
CAS号:
分子量:
186.85
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

$117.00


国内现货,预计发货时间2025年4月07日详情


获取大包装报价

表单

powder

组成

Fe, 29%

反应适用性

core: iron
reagent type: ligand
reaction type: Cross Couplings

官能团

amine
phosphine

SMILES字符串

O.O.[Fe+3].[O-]P([O-])([O-])=O

InChI

1S/Fe.H3O4P.2H2O/c;1-5(2,3)4;;/h;(H3,1,2,3,4);2*1H2/q+3;;;/p-3

InChI key

BMTOKWDUYJKSCN-UHFFFAOYSA-K

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应用

磷酸铁(III)二水合物(FePO4 x 2H2O)可作为催化剂用于:
  • 通过醛、β-酮酸酯和尿素/硫脲的一锅三组分Biginelli反应生成3,4-二氢嘧啶-2(1H)-酮和硫酮。[1]
  • 通过异丁酸甲酯(MIB)的氧化脱氢反应生成甲基丙烯酸甲酯(MMA)。[2]

还用于合成碳包覆磷酸铁锂(LiFePO4),作为锂离子电池的正极材料。[3][4][5]它还是制备磷酸盐玻璃纤维的主要原料。[6]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Yajing Yin et al.
Chemical communications (Cambridge, England), 48(15), 2137-2139 (2012-01-17)
Amorphous FePO(4) hollow nanospheres were directly grown on graphene for use as a cathode material in lithium ion batteries. This hybrid exhibits high rate capability and good cycle stability because of efficient Li(+) ion diffusion through the thin wall of
Magnesium coated phosphate glass fibers for unidirectional reinforcement of polycaprolactone composites.
Liu X, et al.
Journal of Biomedical Materials Research. Part B, Applied Biomaterials, 103(7), 1424-1432 (2015)
Wei Wang et al.
Chemical communications (Cambridge, England), 48(58), 7289-7291 (2012-06-16)
Novel iron phosphates microflowers which show SOD-like and peroxidase-like mimic activities were prepared, suggesting potential applications as a biocatalyst and a biosensor for H(2)O(2).
An Oxidative Route for the Production of Methyl Methacrylate: A Study Over Iron Phosphate Catalysts
Harilal A, et al.
Catalysis Letters, 146(7), 1169-1181 (2016)
Iron (III) phosphate dihydrate-catalyzed one-pot synthesis of dihydropyrimidinones and thiones: An improved procedure for the Biginelli reaction
Heravi MM, et al.
Heterocyclic Communications, 12(5), 369-372 (2006)

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. 해당 제품이 결정질인가요 혹은 비정질인가요? is this sample crystalline or amorphous?

    1 answer
    1. This product does not undergo X-ray diffraction testing to validate the crystal structure. Unfortunately, the state of this compound has not been determined.

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