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化驗
≥98.0% (T)
光學活性
[α]20/D −23.5±1°, c = 1.7% in dioxane
mp
127-132 °C
SMILES 字串
CC(C)(C)C(=O)O[C@H]([C@@H](OC(=O)C(C)(C)C)C(O)=O)C(O)=O
InChI
1S/C14H22O8/c1-13(2,3)11(19)21-7(9(15)16)8(10(17)18)22-12(20)14(4,5)6/h7-8H,1-6H3,(H,15,16)(H,17,18)/t7-,8-/m1/s1
InChI 密鑰
UFHJEZDFEHUYCR-HTQZYQBOSA-N
應用
(−)-O,O′-Di-pivaloyl-L-tartaric acid can be used:
- As a chiral staple in the synthesis of helical π-conjugated cyclic nanocoils, which are used as nano springs, nano solenoids, and pressure sensors.
- As an additive in the iridium-catalyzed C-H amidation reactions of arylphosphoryl compounds.
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Versatile Bottom-up Approach to Stapled π-Conjugated Helical Scaffolds: Synthesis and Chiroptical Properties of Cyclic o-Phenylene Ethynylene Oligomers
Angewandte Chemie (International Edition in English), 124(52), 13213-13217 (2012)
Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C--H amidation
Tetrahedron, 71(26-27), 4504-4511 (2015)
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