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方案
99%
mp
86-88 °C (lit.)
官能团
ester
SMILES字符串
COC(=O)c1cc(O)ccc1O
InChI
1S/C8H8O4/c1-12-8(11)6-4-5(9)2-3-7(6)10/h2-4,9-10H,1H3
InChI key
XGDPKUKRQHHZTH-UHFFFAOYSA-N
一般描述
Methyl 2,5-dihydroxybenzoate (methyl gentisate) is an alkyl ester of gentisic acid. It is reported to show less cytotoxic and mutagenic activity than hydroquinone with a potential to inhibit melanogenesis.[1] It has been synthesized from 2,5-dihydroxybenzoic acid. The crystal structure of the molecule was found to be planar.[2]
应用
Methyl 2,5-dihydroxybenzoate (methyl gentisate) may be used as a starting material in the synthesis of euonyminol.[3]
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
E V Curto et al.
Biochemical pharmacology, 57(6), 663-672 (1999-02-26)
To discover safe and effective topical skin-lightening agents, we have evaluated alkyl esters of the natural product gentisic acid (GA), which is related to our lead compound methyl gentisate (MG), and four putative tyrosinase inhibitors, utilizing mammalian melanocyte cell cultures
Methyl 2, 5-dihydroxybenzoate.
Brown CL, et al.
Acta Crystallographica Section E, Structure Reports Online, 59(5), 630-631 (2003)
Total Synthesis of (.+-.)-Euonyminol, the Sesquiterpenoid Nucleus of Cathedulin K-19, via an Epoxide Cascade Cyclization.
White JD, et al.
Journal of the American Chemical Society, 117(38), 9780-9781 (1995)
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