425206

2-(甲硫基)环己酮

98%

• 线性分子式: CH₃SC₆H₉(=O)
• CAS号: 52190-35-9
• 分子量: 144.23
• MDL编号: MFCD00209603
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24866619

属性

• 方案: 98%
• 表单: liquid
• 折射率: n20/D 1.508 (lit.)
• 沸点: 45 °C/10.1 mmHg (lit.)
• 密度: 1.069 g/mL at 25 °C (lit.)
• SMILES字符串: CSC1CCCCC1=O
• InChI: 1S/C7H12OS/c1-9-7-5-3-2-4-6(7)8/h7H,2-5H2,1H3
• InChI key: QFABNUVNDKOIEH-UHFFFAOYSA-N

说明

一般描述

2-(Methylthio)cyclohexanone is a 2-substituted cyclohexanone. The proportion of axial and equatorial conformation has been measured in chloroform by the Eliel method. It suggests that the in chloroform steric effect dominates over polar effect in contributing to the conformational preference. The stereoselectivity of the reduction of 2-(methylthio)cyclohexanone using different hydrides has been studied.

应用

2-(Methylthio)cyclohexanone may be used as a ketone substrate for the synthesis of cyclic nitrones, by reacting with aspergillusol A.

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 10 - Combustible liquids
• WGK: WGK 3
• 闪点(°F): 192.2 °F - closed cup
• 闪点(°C): 89 °C - closed cup
• 个人防护装备: Eyeshields, Gloves, type ABEK (EN14387) respirator filter