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422460

Sigma-Aldrich

2-醛基噻唑

97%

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1 G
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1 G
$127.00

About This Item

经验公式（希尔记法）:
C4H3NOS
CAS号:
10200-59-6
分子量:
113.14
MDL號碼:
MFCD00142924
分類程式碼代碼:
12352100
PubChem物質ID:
24866433
NACRES:
NA.22
形狀:
liquid
化驗:
97%

$127.00

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品質等級

100

化驗

97%

形狀

liquid

折射率

n20/D 1.574 (lit.)

bp

61-63 °C/15 mmHg (lit.)

密度

1.288 g/mL at 25 °C (lit.)

官能基

aldehyde

儲存溫度

2-8°C

SMILES 字串

O=Cc1nccs1

InChI

1S/C4H3NOS/c6-3-4-5-1-2-7-4/h1-3H

InChI 密鑰

ZGTFNNUASMWGTM-UHFFFAOYSA-N

相关类别

一般說明

2-Thiazolecarboxaldehyde is a thiazole aldehyde derivative. It undergoes Baylis–Hillman reaction with methyl acrylate catalyzed by DABCO (1,4-diazabicyclo[2.2.2]octane). The reaction mechanism has been studied by electrospray ionization mass spectrometry (ESI-MS).[1][2]

應用

紫杉烷类似物的有用结构单元。[3]
2-Thiazolecarboxaldehyde may be used as a reactant in the following syntheses:
  • Benzothiazine N-acylhydrazones, having potential antinociceptive and anti-inflammatory activity.[4]
  • Thiazole-2-yl-(amino)methylphosphonate diethyl esters.[5]
  • Imino ester by reacting with L-leucine t-butyl ester hydrochloride.[6]

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

154.4 °F - closed cup

閃點（°C）

68 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCF7118
MKBT3230V
MKBH5972
MKBG6814
MKBF0973

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Online mechanistic investigations of catalyzed reactions by electrospray ionization mass spectrometry: a tool to intercept transient species in solution.
Santos LS.
European Journal of Organic Chemistry, 2008(2), 235-253 (2008)
Synthesis of new thiazole-2,-4, and-5-yl-(amino) methylphosphonates and phosphinates: unprecedented cleavage of thiazole-2 derivatives under acidic conditions.
Olszewski TK and Boduszek B.
Tetrahedron, 66(45), 8661-8866 (2010)
Armel A Agbodjan et al.
The Journal of organic chemistry, 73(8), 3094-3102 (2008-03-25)
A practical asymmetric synthesis of a highly substituted N-acylpyrrolidine on multi-kilogram scale is described. The key step in the construction of the three stereocenters is a [3+2] cycloaddition of methyl acrylate and an imino ester prepared from l-leucine t-butyl ester
The Morita-Baylis-Hillman Reaction: Advances and Contributions from Brazilian Chemistry.
Santos MS, et al.
Current Organic Synthesis, 12(6), 830-852 (2015)
Yasuyuki Takeda et al.
Bioorganic & medicinal chemistry letters, 14(12), 3209-3215 (2004-05-20)
To improve the metabolic stability of 3, which exhibited both in vitro antitumor activity and in vivo efficacy by both iv and po administration, we designed and synthesized new taxane analogues. Most of the synthetic compounds maintained excellent antitumor activity
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