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About This Item
线性分子式:
O2NCH=C(SCH3)NHCH3
CAS号:
分子量:
148.18
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗
98%
形狀
solid
mp
112-118 °C (lit.)
官能基
amine
nitro
thioether
SMILES 字串
CN\C(SC)=C/[N+]([O-])=O
InChI
1S/C4H8N2O2S/c1-5-4(9-2)3-6(7)8/h3,5H,1-2H3/b4-3+
InChI 密鑰
YQFHPXZGXNYYLD-ONEGZZNKSA-N
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應用
(E) N-methyl-1-(methylthio)-2-nitroethenamine) (NMSM) may be used for the following syntheses:
- pyrano[2,3-c]pyrazol-6-amines
- 6-methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Selvaraj Kanchithalaivan et al.
ACS combinatorial science, 15(12), 631-638 (2013-10-24)
An efficient one-pot four-component domino protocol for the combinatorial synthesis of novel 1,4-dihydropyrano[2,3-c]pyrazol-6-amines has been achieved. This transformation presumably occurs via cyclization-Knoevenagel condensation-Michael addition-tautomerism-intramolecular O-cyclization-elimination sequence of reactions. The significant features of this reaction include expedient one-pot process, short reaction
6-Methoxy-N-methyl-3-nitro-4-nitromethyl-4H-chromen-2-amine.
Muthukumaran J, et al.
Acta Crystallographica Section E, Structure Reports Online, 67(5), 1276-1277 (2011)
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