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Merck

414670

Sigma-Aldrich

1-碘-2-三甲基硅基乙炔

97%

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About This Item

线性分子式:
(CH3)3SiC≡CI
CAS号:
分子量:
224.11
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

liquid

折射率

n20/D 1.511 (lit.)

bp

130 °C (lit.)

密度

1.46 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C[Si](C)(C)C#CI

InChI

1S/C5H9ISi/c1-7(2,3)5-4-6/h1-3H3

InChI 密鑰

HNIRHTRSZDSMOF-UHFFFAOYSA-N

應用

1-Iodo-2-(trimethylsilyl)acetylene may be used to investigate the reactivity of diamagnetic cobalt(I) complex, Tol-BDI((2-pp)2)Co [Tol-BDI((2-pp)2)H = 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine]. It may be used for the synthesis of 1-(4-trimethylsilanylbuta-1,3-diynyl)pyrene, via Pd-coupling with 1-iodo-2-trimethylsilylacetylene.

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Repr. 2 - Resp. Sens. 1 - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

118.4 °F - closed cup

閃點(°C)

48 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Slide 1 of 2

1 of 2

Elodie E Marlier et al.
Inorganic chemistry, 51(4), 2079-2085 (2012-02-11)
A model for cobalamin was synthesized using a new monoanionic tetradentate nitrogen donor ligand; 2-(4-tolyl)-1,3-bis(2-isopropylpyridyl)propenediimine (Tol-BDI((2-pp)2)H) (1), which utilizes isopropylpyridines as pendant arms on a β-diketiminate (BDI) backbone. During the synthesis of 1, the rearrangement product, Tol-BDI((2-pp)(4-pp))H (2) was observed.
Novel polyacetylenes containing pendant 1-pyrenyl groups: synthesis, characterization, and thermal and optical properties.
Rivera E, et al.
Polymer, 43(19), 5059-5068 (2009)

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