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410608

Sigma-Aldrich

4-(苄氧基)吡啶N-氧化物

97%

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About This Item

经验公式（希尔记法）:
C12H11NO2
CAS号:
2683-66-1
分子量:
201.22
MDL编号:
MFCD00047427
UNSPSC代码:
12352100
PubChem化学物质编号:
24865537
NACRES:
NA.22

方案

97%

mp

178-179 °C (dec.) (lit.)

SMILES字符串

[O-][n+]1ccc(OCc2ccccc2)cc1

InChI

1S/C12H11NO2/c14-13-8-6-12(7-9-13)15-10-11-4-2-1-3-5-11/h1-9H,10H2

InChI key

SUSQPKJQYWTFPU-UHFFFAOYSA-N

一般描述

4-(Benzyloxy)pyridine N-oxide is a 4-substituted pyridine-1-oxide.[1] It undergoes hydrogenation over palladium to afford pyridine.[1] It participates in the stereoselective synthesis of substituted pyridines, piperidines and piperazines.[2]

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBK3273V
MKBJ8691V
MKBD4918
MKAA4156
MKAA4724

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Hans Andersson et al.
Organic & biomolecular chemistry, 9(2), 337-346 (2010-11-16)
In this perspective we discuss the recent developments of stereoselective synthesis of substituted pyridines, piperidines, and piperazines from cheap and commercially readily available starting materials. Pyridine N-oxides and pyrazine N-oxides are reacted with alkyl, aryl, alkynyl and vinyl Grignard reagents
248. N-oxides and related compounds. Part X. The hydrogenation of some pyridine 1-oxides.
Katritzky AR and Monro AM.
Journal of the Chemical Society, 1263-1266 (1958)

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