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Merck

406317

Sigma-Aldrich

异丙基-9H-噻吨-9-酮(2、4位异构体混合物)

97%

别名:

Isopropyl-9H -thioxanthen-9-one, Isopropylthioxanthone

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$274.00

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25 G
$94.60
100 G
$274.00

About This Item

经验公式(希尔记法):
C16H14OS
CAS号:
分子量:
254.35
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.25

$94.60


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品質等級

化驗

97%

SMILES 字串

CC(C)c1cccc2C(=O)c3ccccc3Sc12

InChI

1S/C16H14OS/c1-10(2)11-7-5-8-13-15(17)12-6-3-4-9-14(12)18-16(11)13/h3-10H,1-2H3

InChI 密鑰

IKVYHNPVKUNCJM-UHFFFAOYSA-N

一般說明

Isopropylthioxanthone(ITX) is a thioxanthone derivative widely utilized as a photoinitiator in polymerization processes. It is available as a mixture of 2- and 4- isomers. It breaks down into free radicals upon exposure to ultraviolet radiation, initiating polymerization in UV curing inks, wood coatings, paper coatings, optical fiber, screen printing, and paper varnish.

應用

Isopropylthioxanthone can be used as:
  • A photoinitiator along with azolium tetraphenylborate to N-heterocyclic carbene (NHC) generation in the synthesis of polyurethane, polyester, and ROMP (ring-opening metathesis polymerization) polymers. The mixture of ITX and azolium tetraphenylborate serves as an air-stable NHC photogenerator, activated by irradiation at 365 nm.
  • A photocatalyst to facilitate the functionalization of bicyclo[1.1.0]butanes. This approach allows for the introduction of various functional groups onto the bicyclo[1.1.0]butane framework.
  • A sensitizer that absorbs light and transfers energy to di(tert-butylphenyl)iodonium salts, facilitating their photolysis. This process generates reactive species necessary for initiating polymerization reactions. This sensitization approach is useful in various fields, including coatings, adhesives, and dental materials, where controlled polymerization is essential.

象形圖

Health hazardEnvironment

訊號詞

Warning

危險聲明

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Questions

  1. What is the wavelength of maximum light absorption of 406317

    1 answer
    1. We do not have a UV-Vis spectrum for either Product 406317 (Isopropyl-9H-thioxanthen-9-one, mixture of 2- and 4-isomers) or the closely related Product 406368 (2,4-Diethyl-9H-thioxanthen-9-one). Given that they are both typically yellow, one might expect absorbance around 420-450 nm.
      This is not necessarily the maximum, but it would be a reasonable wavelength range to try.

      Helpful?

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