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Merck

406023

Sigma-Aldrich

二乙基锌 溶液

1.0 M in heptane

别名:

Zincdiethyl

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About This Item

线性分子式:
(C2H5)2Zn
CAS号:
分子量:
123.51
Beilstein:
3587207
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

濃度

1.0 M in heptane

bp

98 °C

密度

0.74 g/mL at 25 °C

SMILES 字串

CC[Zn]CC

InChI

1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;

InChI 密鑰

HQWPLXHWEZZGKY-UHFFFAOYSA-N

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應用

二乙基锌溶液可用于合成:
  • 双(吡啶基吡咯基)锌发光配合物。
  • 通用构件块,5-(酮芳基)噻唑。
  • 具有高发光性能的 ZnxCd1-xSe 纳米晶体。

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system

安全危害

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

12.2 °F - closed cup

閃點(°C)

-11 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Composition-Tunable ZnxCd1-xSe nanocrystals with high luminescence and stability.
Xinhua Z, et al.
Journal of the American Chemical Society, 125(28), 8589-8594 (2003)
Pyridylpyrrolides as alternatives to cyclometalated phenylpyridine ligands: synthesis and characterization of luminescent zinc and boron pyridylpyrrolide complexes.
Klappa JJ, et al.
Dalton Transactions, 883-891 (2004)
Practical synthesis of a highly functionalized thiazole ketone.
Frey LF, et al.
Tetrahedron, 59(33), 6363-6373 (2003)
Weimin Lin et al.
The Journal of organic chemistry, 74(2), 645-651 (2008-12-06)
The application of a zinc carbenoid-mediated chain-extension reaction to a functionalized peptide isostere is reported. The cleavage site of human CVM protease was utilized as a target for testing the synthetic methodology. The utility of this chain-extension reaction is demonstrated
Isabelle Bonnaventure et al.
The Journal of organic chemistry, 73(16), 6330-6340 (2008-07-22)
The hemilabile ligand Me-DuPHOS(O) 2 has proven to be a successful ligand for the copper-catalyzed addition of diethylzinc to N-phosphinoylimines. The corresponding alpha-chiral amines were obtained in high yields (80-98%) and enantiomeric ratios (19.0:1 to 99.0:1 er). Furthermore, this Cu*

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