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About This Item
线性分子式:
CH3CH2CH2COOCH2CF3
CAS号:
分子量:
170.13
Beilstein:
1769212
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
推荐产品
化驗
98%
折射率
n20/D 1.347 (lit.)
bp
113 °C/747 mmHg (lit.)
密度
1.127 g/mL at 25 °C (lit.)
SMILES 字串
CCCC(=O)OCC(F)(F)F
InChI
1S/C6H9F3O2/c1-2-3-5(10)11-4-6(7,8)9/h2-4H2,1H3
InChI 密鑰
DEXWRCYOMLUJRF-UHFFFAOYSA-N
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一般說明
Solvent effects on porcine pancreatic lipase-catalyzed transesterification of 2,2,2-trifluoroethyl butyrate has been studied. Kinetics of the reaction of OH radicals and Cl atoms with 2,2,2 trifluoroethyl butyrate has been reported.
應用
2,2,2-Trifluoroethyl butyrate may be used in the lipase catalyzed resolution of unsubstituted and N-alkyl substituted 2-amino-1-phenylethanols. It may be used in the synthesis of enantiomerically pure (R)- or (S)-1-aminoindane.
訊號詞
Danger
危險分類
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
69.8 °F - closed cup
閃點（°C）
21 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Lipase catalysis in the optical resolution of 2-amino-1-phenylethanol derivatives.
Kanerva LT, et al.
Journal of the Chemical Society. Perkin Transactions 1, 14, 1759-1762 (1992)
Tropospheric degradation of 2, 2, 2 trifluoroethyl butyrate: Kinetic study of their reactions with OH radicals and Cl atoms at 298K.
Blanco MB, et al.
Chemical Physics Letters, 578, 33-37 (2013)
W H Boesten et al.
Organic letters, 3(8), 1121-1124 (2001-05-12)
[reaction: see text]. Diastereoselective Strecker reactions based on (R)-phenylglycine amide as chiral auxiliary are reported. The Strecker reaction is accompanied by an in situ crystallization-induced asymmetric transformation, whereby one diastereomer selectively precipitates and can be isolated in 76-93% yield and
L T Kanerva et al.
Acta chemica Scandinavica (Copenhagen, Denmark : 1989), 44(10), 1032-1035 (1990-11-01)
Porcine pancreatic lipase-catalysed transesterifications of 2,2,2-trifluoroethyl butyrate with racemic 2-octanol and 1-phenylethanol have been studied in different organic solvents. Solvent hydrophobicity (log P -1.1 to 3.3) has only a minor effect on the reaction rate. Independently of the solvent used
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